Quinquethiophene (C20H12S5) - excitons of #1040

CAM-B3LYP def2-TZVP 50 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B1 1.989 3.014 eV
S2 A1 0.003 3.917 eV
S3 A1 0.000 4.274 eV
S4 B1 0.098 4.573 eV
S5 A1 0.002 4.950 eV
S6 A1 0.009 4.979 eV
S7 B1 0.018 5.007 eV
S8 B2 0.000 5.067 eV
S9 A2 0.000 5.094 eV
S10 B1 0.007 5.148 eV
S11 B2 0.001 5.201 eV
S12 A1 0.089 5.313 eV
S13 B1 0.029 5.358 eV
S14 B1 0.005 5.486 eV
S15 A2 0.000 5.501 eV
S16 B2 0.000 5.544 eV
S17 A1 0.090 5.585 eV
S18 A1 0.039 5.770 eV
S19 B1 0.025 6.051 eV
S20 A2 0.000 6.053 eV
S21 A2 0.000 6.081 eV
S22 B2 0.000 6.111 eV
S23 A2 0.000 6.126 eV
S24 B1 0.139 6.181 eV
S25 A1 0.004 6.212 eV
S26 B1 0.012 6.259 eV
S27 A1 0.001 6.308 eV
S28 B2 0.000 6.331 eV
S29 A2 0.000 6.337 eV
S30 A2 0.000 6.455 eV
S31 A1 0.001 6.466 eV
S32 B1 0.005 6.467 eV
S33 A1 0.001 6.496 eV
S34 B2 0.000 6.500 eV
S35 B2 0.006 6.590 eV
S36 B1 0.006 6.644 eV
S37 A2 0.000 6.710 eV
S38 B2 0.000 6.755 eV
S39 A2 0.000 6.758 eV
S40 A1 0.259 6.848 eV
S41 B2 0.000 6.849 eV
S42 A2 0.000 6.864 eV
S43 B2 0.002 6.882 eV
S44 A2 0.000 6.930 eV
S45 B1 0.005 6.934 eV
S46 A1 0.076 6.963 eV
S47 A2 0.000 7.069 eV
S48 A2 0.000 7.072 eV
S49 A1 0.000 7.091 eV
S50 B1 0.062 7.100 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -75102.53

Code Orca 6.1.0

Author Peter Puschnig

Date 2025-06-10 16:02:51

Added 2026-08-20 13:56:54

Legacy ID None

System


Full Name Quinquethiophene

Short Name 5T

Formula C20H12S5

Mass 412.6 u

Point Group C2v

Orientation xz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
22 B3LYP 6-31G* NWChem 0.0 0.0 15
170 6-31G* NWChem -1.0 0.5 169
757 cc-pVTZ NWChem 0.0 0.0
881 cc-pVTZ Orca 0.0 0.0
1040 CAM-B3LYP def2-TZVP Orca 0.0 0.0
104 HSE06 6-31G* NWChem 0.0 0.0 102
63 PBE 6-31G* NWChem 0.0 0.0 60
610 PBE0 6-31G* NWChem 0.0 0.0 623
649 6-31G* NWChem 0.0 0.0 664

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM