Phenanthrene (C14H10) - #1042

CAM-B3LYP def2-TZVP q = 0 2S+1 = 1 Orbitals Excitons

REAL SPACE

MOMENTUM SPACE (Ekin = 30 eV)

ORBITALS

LUMO+3 A2 0 1.864 eV
LUMO+2 B2 0 0.987 eV
LUMO+1 B2 0 -0.073 eV
LUMO A2 0 -0.190 eV
HOMO B2 2 -7.323 eV
HOMO-1 A2 2 -7.640 eV
HOMO-2 A2 2 -8.841 eV
HOMO-3 B2 2 -9.531 eV
HOMO-4 B2 2 -10.506 eV
HOMO-5 B1 2 -10.601 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -14670.07

Code Orca 6.1.0

Author Peter Puschnig

Date 2025-06-10 16:02:51

Added 2026-08-20 13:57:29

Legacy ID None

System


Full Name Phenanthrene

Short Name 3phenacene

Formula C14H10

Mass 178.2 u

Point Group C2v

Orientation xz

Further Reading

Further Reading Phenanthrene

  1. Simulation of angle-resolved photoemission spectra by approximating the final state by a plane wave: from graphene to polycyclic aromatic hydrocarbon molecules

    P. Puschnig and D. Lüftner

    J. Elec. Spec. Rel. Phen. 200, 193 (2015)

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening
Energy Axis
Peak Scaling

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere
ID XC Functional Basis Set Code Charge Spin Casida Legacy
24 B3LYP 6-31G* NWChem 0.0 0.0 17
172 6-31G* NWChem -1.0 0.5 171
746 cc-pVTZ NWChem 0.0 0.0
979 cc-pVTZ Orca 0.0 0.0
1042 CAM-B3LYP def2-TZVP Orca 0.0 0.0
106 HSE06 6-31G* NWChem 0.0 0.0 104
144 OT-RSH 6-31G* NWChem 0.0 0.0 142
65 PBE 6-31G* NWChem 0.0 0.0 62
597 PBE0 6-31G* NWChem 0.0 0.0 610
637 6-31G* NWChem 0.0 0.0 651

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ENERGY SPECTRUM