Ni-5,6-dihydro-1,4-dithiin-2,3-dithiolate (C8H8NiS8) - excitons of #1083

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B 0.716 1.803 eV
S2 A 0.000 1.851 eV
S3 B 0.000 2.080 eV
S4 A 0.000 2.291 eV
S5 B 0.000 2.456 eV
S6 A 0.000 2.468 eV
S7 B 0.005 2.734 eV
S8 A 0.000 2.761 eV
S9 A 0.000 2.854 eV
S10 B 0.009 2.944 eV
S11 A 0.002 3.078 eV
S12 A 0.000 3.457 eV
S13 B 0.000 3.482 eV
S14 B 0.109 3.576 eV
S15 A 0.001 3.736 eV
S16 A 0.000 4.000 eV
S17 A 0.000 4.019 eV
S18 B 0.001 4.065 eV
S19 B 0.101 4.394 eV
S20 B 0.008 4.412 eV
S21 A 0.000 4.707 eV
S22 B 0.003 4.796 eV
S23 A 0.001 4.921 eV
S24 B 0.019 5.019 eV
S25 B 0.009 5.055 eV
S26 A 0.000 5.101 eV
S27 B 0.094 5.124 eV
S28 A 0.009 5.189 eV
S29 B 0.506 5.334 eV
S30 B 0.189 5.340 eV
S31 A 0.002 5.384 eV
S32 B 0.740 5.472 eV
S33 A 0.000 5.536 eV
S34 B 1.184 5.599 eV
S35 A 0.003 5.604 eV
S36 A 0.000 5.615 eV
S37 B 0.132 5.676 eV
S38 B 0.201 5.746 eV
S39 A 0.000 5.764 eV
S40 A 0.018 5.846 eV
S41 A 0.007 5.948 eV
S42 A 0.000 6.083 eV
S43 B 0.001 6.084 eV
S44 A 0.017 6.105 eV
S45 B 0.030 6.152 eV
S46 B 0.091 6.212 eV
S47 B 0.020 6.258 eV
S48 A 0.000 6.301 eV
S49 A 0.003 6.322 eV
S50 B 0.006 6.356 eV
S51 B 0.003 6.375 eV
S52 A 0.000 6.382 eV
S53 B 0.047 6.398 eV
S54 A 0.000 6.490 eV
S55 B 0.000 6.504 eV
S56 A 0.000 6.559 eV
S57 A 0.000 6.590 eV
S58 A 0.002 6.591 eV
S59 B 0.065 6.603 eV
S60 B 0.010 6.617 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -136153.96

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-08-28 21:14:14

Legacy ID None

System


Full Name Ni-5,6-dihydro-1,4-dithiin-2,3-dithiolate

Short Name Ni(dddt)2

Formula C8H8NiS8

Mass 419.3 u

Point Group C2

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1083 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM