1-Bromopyrene (C16H9Br) - excitons of #1119

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.005 4.030 eV
S2 A' 0.440 4.137 eV
S3 A' 0.002 4.812 eV
S4 A' 0.001 5.141 eV
S5 A' 0.548 5.328 eV
S6 A" 0.000 5.516 eV
S7 A' 0.002 5.597 eV
S8 A' 0.474 5.846 eV
S9 A' 0.214 5.884 eV
S10 A' 0.044 5.979 eV
S11 A' 0.641 6.046 eV
S12 A" 0.000 6.235 eV
S13 A' 0.030 6.604 eV
S14 A" 0.000 6.634 eV
S15 A" 0.000 6.696 eV
S16 A' 0.016 6.784 eV
S17 A' 0.059 6.828 eV
S18 A' 0.000 6.885 eV
S19 A" 0.000 6.916 eV
S20 A" 0.000 6.930 eV
S21 A' 0.035 6.951 eV
S22 A" 0.000 7.080 eV
S23 A' 0.953 7.132 eV
S24 A" 0.000 7.168 eV
S25 A" 0.001 7.276 eV
S26 A' 0.469 7.318 eV
S27 A' 0.202 7.416 eV
S28 A" 0.001 7.432 eV
S29 A" 0.001 7.450 eV
S30 A" 0.001 7.659 eV
S31 A' 0.939 7.678 eV
S32 A" 0.000 7.690 eV
S33 A" 0.000 7.766 eV
S34 A' 0.114 7.781 eV
S35 A' 0.258 7.839 eV
S36 A" 0.007 7.839 eV
S37 A" 0.007 7.846 eV
S38 A" 0.000 7.950 eV
S39 A" 0.000 8.015 eV
S40 A' 0.156 8.035 eV
S41 A" 0.000 8.051 eV
S42 A" 0.000 8.094 eV
S43 A' 0.058 8.118 eV
S44 A" 0.000 8.118 eV
S45 A' 0.060 8.198 eV
S46 A" 0.003 8.218 eV
S47 A" 0.000 8.230 eV
S48 A' 0.013 8.251 eV
S49 A" 0.000 8.299 eV
S50 A' 0.053 8.432 eV
S51 A" 0.003 8.447 eV
S52 A" 0.000 8.507 eV
S53 A" 0.000 8.543 eV
S54 A' 0.079 8.546 eV
S55 A" 0.002 8.565 eV
S56 A" 0.004 8.577 eV
S57 A" 0.000 8.637 eV
S58 A" 0.002 8.690 eV
S59 A" 0.000 8.702 eV
S60 A" 0.000 8.742 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -86776.75

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:22:09

Legacy ID None

System


Full Name 1-Bromopyrene

Short Name 1-bromopyrene

Formula C16H9Br

Mass 281.2 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1119 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM