11-Methylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C21H14) - excitons of #1146

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.044 3.971 eV
S2 A' 0.021 4.158 eV
S3 A' 0.308 4.177 eV
S4 A' 0.189 4.784 eV
S5 A' 0.218 5.067 eV
S6 A' 0.330 5.267 eV
S7 A' 0.936 5.541 eV
S8 A' 0.181 5.683 eV
S9 A' 0.104 5.713 eV
S10 A' 0.922 5.957 eV
S11 A' 0.034 6.162 eV
S12 A' 0.126 6.335 eV
S13 A' 0.209 6.424 eV
S14 A' 0.127 6.515 eV
S15 A" 0.000 6.534 eV
S16 A' 0.163 6.583 eV
S17 A' 0.070 6.671 eV
S18 A' 0.195 6.699 eV
S19 A" 0.000 6.723 eV
S20 A' 0.069 6.810 eV
S21 A' 0.057 6.946 eV
S22 A" 0.000 7.117 eV
S23 A' 0.461 7.119 eV
S24 A" 0.001 7.160 eV
S25 A" 0.000 7.231 eV
S26 A' 0.055 7.242 eV
S27 A" 0.000 7.265 eV
S28 A" 0.001 7.280 eV
S29 A" 0.000 7.310 eV
S30 A" 0.000 7.357 eV
S31 A' 0.018 7.368 eV
S32 A' 0.072 7.404 eV
S33 A" 0.000 7.463 eV
S34 A" 0.006 7.489 eV
S35 A' 0.247 7.572 eV
S36 A" 0.002 7.598 eV
S37 A' 0.064 7.637 eV
S38 A" 0.000 7.661 eV
S39 A" 0.003 7.690 eV
S40 A" 0.000 7.711 eV
S41 A" 0.005 7.758 eV
S42 A' 0.104 7.781 eV
S43 A" 0.001 7.835 eV
S44 A' 0.387 7.850 eV
S45 A" 0.000 7.873 eV
S46 A' 0.150 7.896 eV
S47 A" 0.000 7.952 eV
S48 A" 0.000 8.024 eV
S49 A" 0.000 8.046 eV
S50 A" 0.000 8.068 eV
S51 A" 0.001 8.082 eV
S52 A' 0.194 8.143 eV
S53 A" 0.002 8.191 eV
S54 A' 0.130 8.211 eV
S55 A" 0.000 8.216 eV
S56 A' 0.016 8.254 eV
S57 A" 0.000 8.269 eV
S58 A' 0.010 8.280 eV
S59 A" 0.000 8.332 eV
S60 A' 0.050 8.348 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21992.57

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:27:12

Legacy ID None

System


Full Name 11-Methylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name 1-methylbenzo(b)fluoranthene

Formula C21H14

Mass 266.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1146 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM