3-Methylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C21H14) - excitons of #1170

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.043 3.991 eV
S2 A' 0.260 4.150 eV
S3 A' 0.069 4.196 eV
S4 A' 0.129 4.805 eV
S5 A' 0.220 5.067 eV
S6 A' 0.306 5.291 eV
S7 A' 1.104 5.497 eV
S8 A' 0.065 5.640 eV
S9 A' 0.203 5.737 eV
S10 A' 0.730 5.963 eV
S11 A' 0.046 6.171 eV
S12 A' 0.190 6.292 eV
S13 A' 0.294 6.385 eV
S14 A" 0.000 6.560 eV
S15 A' 0.083 6.596 eV
S16 A' 0.009 6.662 eV
S17 A' 0.028 6.667 eV
S18 A" 0.000 6.672 eV
S19 A' 0.200 6.751 eV
S20 A' 0.245 6.855 eV
S21 A' 0.091 6.935 eV
S22 A" 0.000 7.074 eV
S23 A' 0.392 7.096 eV
S24 A" 0.001 7.186 eV
S25 A' 0.042 7.197 eV
S26 A" 0.001 7.224 eV
S27 A" 0.002 7.244 eV
S28 A' 0.012 7.321 eV
S29 A" 0.001 7.342 eV
S30 A" 0.001 7.343 eV
S31 A" 0.003 7.418 eV
S32 A" 0.000 7.467 eV
S33 A' 0.092 7.472 eV
S34 A" 0.005 7.480 eV
S35 A' 0.129 7.564 eV
S36 A' 0.065 7.597 eV
S37 A" 0.000 7.623 eV
S38 A" 0.000 7.638 eV
S39 A" 0.003 7.695 eV
S40 A' 0.139 7.702 eV
S41 A" 0.002 7.727 eV
S42 A" 0.000 7.767 eV
S43 A" 0.002 7.839 eV
S44 A' 0.547 7.851 eV
S45 A" 0.002 7.864 eV
S46 A' 0.027 7.908 eV
S47 A" 0.000 7.986 eV
S48 A" 0.000 8.039 eV
S49 A" 0.000 8.059 eV
S50 A" 0.000 8.070 eV
S51 A' 0.081 8.092 eV
S52 A" 0.003 8.116 eV
S53 A' 0.293 8.173 eV
S54 A" 0.003 8.203 eV
S55 A" 0.000 8.248 eV
S56 A" 0.000 8.261 eV
S57 A' 0.040 8.307 eV
S58 A" 0.002 8.313 eV
S59 A' 0.118 8.346 eV
S60 A" 0.000 8.349 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21992.53

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:32:13

Legacy ID None

System


Full Name 3-Methylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name 12-methylbenzo(b)fluoranthrene

Formula C21H14

Mass 266.3 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1170 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM