6-Nitrohexacyclo[16.3.1.02,7.08,21.011,20.014,19]docosa-1(22),2(7),3,5,8(21),9,11(20),12,14(19),15,17-undecaene (C22H11NO2) - excitons of #1171

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.273 3.447 eV
S2 0.089 3.837 eV
S3 0.109 3.981 eV
S4 0.117 4.009 eV
S5 0.109 4.123 eV
S6 0.196 4.444 eV
S7 0.008 4.645 eV
S8 0.054 4.854 eV
S9 0.048 4.946 eV
S10 0.048 5.019 eV
S11 0.425 5.115 eV
S12 0.042 5.408 eV
S13 0.052 5.557 eV
S14 0.062 5.648 eV
S15 0.420 5.752 eV
S16 0.015 5.816 eV
S17 0.256 5.982 eV
S18 0.644 6.025 eV
S19 0.000 6.099 eV
S20 0.570 6.126 eV
S21 0.219 6.241 eV
S22 0.023 6.308 eV
S23 0.004 6.360 eV
S24 0.283 6.446 eV
S25 0.010 6.513 eV
S26 0.032 6.603 eV
S27 0.134 6.662 eV
S28 0.209 6.702 eV
S29 0.006 6.765 eV
S30 0.060 6.799 eV
S31 0.180 6.843 eV
S32 0.028 6.856 eV
S33 0.170 6.908 eV
S34 0.140 6.960 eV
S35 0.000 7.033 eV
S36 0.043 7.054 eV
S37 0.146 7.135 eV
S38 0.006 7.162 eV
S39 0.012 7.186 eV
S40 0.058 7.197 eV
S41 0.457 7.254 eV
S42 0.010 7.339 eV
S43 0.205 7.380 eV
S44 0.256 7.408 eV
S45 0.011 7.426 eV
S46 0.022 7.461 eV
S47 0.085 7.461 eV
S48 0.012 7.545 eV
S49 0.226 7.590 eV
S50 0.093 7.612 eV
S51 0.004 7.620 eV
S52 0.027 7.645 eV
S53 0.026 7.684 eV
S54 0.015 7.713 eV
S55 0.076 7.731 eV
S56 0.017 7.735 eV
S57 0.031 7.779 eV
S58 0.020 7.803 eV
S59 0.017 7.831 eV
S60 0.067 7.849 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -28562.85

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:32:28

Legacy ID None

System


Full Name 6-Nitrohexacyclo[16.3.1.02,7.08,21.011,20.014,19]docosa-1(22),2(7),3,5,8(21),9,11(20),12,14(19),15,17-undecaene

Short Name 12-nitroindeno(1,2,3-cd)pyrene

Formula C22H11NO2

Mass 321.3 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1171 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM