11,13-Dimethylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C22H16) - excitons of #1180

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.046 3.949 eV
S2 A' 0.031 4.097 eV
S3 A' 0.337 4.171 eV
S4 A' 0.116 4.821 eV
S5 A' 0.180 5.087 eV
S6 A' 0.364 5.209 eV
S7 A' 0.968 5.505 eV
S8 A' 0.232 5.638 eV
S9 A' 0.110 5.715 eV
S10 A' 0.918 5.915 eV
S11 A' 0.116 6.134 eV
S12 A' 0.084 6.308 eV
S13 A' 0.302 6.386 eV
S14 A' 0.115 6.462 eV
S15 A" 0.000 6.523 eV
S16 A' 0.027 6.574 eV
S17 A' 0.093 6.637 eV
S18 A" 0.001 6.658 eV
S19 A' 0.202 6.682 eV
S20 A' 0.059 6.781 eV
S21 A' 0.002 6.890 eV
S22 A" 0.002 7.030 eV
S23 A' 0.437 7.084 eV
S24 A" 0.000 7.095 eV
S25 A' 0.107 7.154 eV
S26 A" 0.001 7.191 eV
S27 A" 0.001 7.223 eV
S28 A" 0.003 7.267 eV
S29 A' 0.072 7.286 eV
S30 A" 0.000 7.287 eV
S31 A" 0.000 7.332 eV
S32 A' 0.086 7.354 eV
S33 A" 0.006 7.390 eV
S34 A" 0.000 7.451 eV
S35 A' 0.156 7.485 eV
S36 A" 0.000 7.509 eV
S37 A" 0.001 7.546 eV
S38 A' 0.193 7.582 eV
S39 A" 0.000 7.628 eV
S40 A' 0.159 7.691 eV
S41 A" 0.006 7.700 eV
S42 A" 0.000 7.716 eV
S43 A" 0.003 7.726 eV
S44 A" 0.000 7.766 eV
S45 A' 0.288 7.789 eV
S46 A' 0.089 7.833 eV
S47 A" 0.000 7.898 eV
S48 A" 0.000 7.905 eV
S49 A" 0.000 7.953 eV
S50 A" 0.001 8.018 eV
S51 A" 0.000 8.048 eV
S52 A" 0.000 8.050 eV
S53 A" 0.000 8.058 eV
S54 A' 0.160 8.064 eV
S55 A" 0.003 8.137 eV
S56 A' 0.031 8.146 eV
S57 A' 0.159 8.216 eV
S58 A' 0.014 8.260 eV
S59 A" 0.000 8.272 eV
S60 A" 0.000 8.299 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -23062.20

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:34:27

Legacy ID None

System


Full Name 11,13-Dimethylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name 1,3-dimethylbenzo(b)fluoranthene

Formula C22H16

Mass 280.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1180 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM