1,3-Diphenylazulene (C22H16) - excitons of #1182

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B 0.013 2.354 eV
S2 A 0.097 3.665 eV
S3 B 0.076 4.736 eV
S4 A 0.776 4.778 eV
S5 B 0.711 4.910 eV
S6 A 0.022 5.025 eV
S7 B 0.003 5.038 eV
S8 A 0.169 5.183 eV
S9 B 0.033 5.482 eV
S10 A 0.001 5.507 eV
S11 B 0.177 5.540 eV
S12 A 0.249 5.656 eV
S13 B 0.033 5.747 eV
S14 A 0.019 5.765 eV
S15 B 0.014 5.792 eV
S16 B 0.000 6.196 eV
S17 A 0.010 6.244 eV
S18 A 0.085 6.259 eV
S19 A 0.099 6.287 eV
S20 B 0.021 6.363 eV
S21 A 0.209 6.401 eV
S22 B 0.175 6.482 eV
S23 B 0.412 6.581 eV
S24 B 0.058 6.723 eV
S25 A 0.029 6.732 eV
S26 B 0.002 6.752 eV
S27 A 0.068 6.772 eV
S28 A 0.015 6.819 eV
S29 A 0.000 6.827 eV
S30 B 0.056 6.884 eV
S31 A 0.117 6.961 eV
S32 B 0.246 6.992 eV
S33 A 0.000 6.995 eV
S34 A 0.002 7.190 eV
S35 B 0.001 7.273 eV
S36 B 0.199 7.299 eV
S37 A 0.084 7.448 eV
S38 A 0.009 7.461 eV
S39 B 0.021 7.514 eV
S40 A 0.599 7.532 eV
S41 B 0.270 7.589 eV
S42 B 0.880 7.604 eV
S43 A 0.112 7.655 eV
S44 B 0.147 7.677 eV
S45 A 0.170 7.715 eV
S46 B 0.132 7.728 eV
S47 A 0.000 7.756 eV
S48 B 0.074 7.779 eV
S49 A 0.000 7.812 eV
S50 B 0.164 7.881 eV
S51 A 0.008 7.883 eV
S52 B 0.031 7.896 eV
S53 A 0.000 7.898 eV
S54 B 0.008 7.907 eV
S55 B 0.002 7.966 eV
S56 A 0.008 7.968 eV
S57 B 0.029 8.003 eV
S58 B 0.009 8.013 eV
S59 A 0.003 8.031 eV
S60 A 0.019 8.036 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -23060.40

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:34:56

Legacy ID None

System


Full Name 1,3-Diphenylazulene

Short Name 1,3-diphenylazulene

Formula C22H16

Mass 280.4 u

Point Group C2

Orientation yz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1182 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM