2,10-Difluoropentacene (C22H12F2) - excitons of #1252

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A1 0.117 2.596 eV
S2 B1 0.013 3.512 eV
S3 B1 0.000 3.851 eV
S4 B1 0.067 3.976 eV
S5 A1 0.013 4.749 eV
S6 B1 5.302 4.925 eV
S7 A1 0.000 4.933 eV
S8 A1 0.011 4.990 eV
S9 B1 0.038 5.383 eV
S10 A1 0.000 5.393 eV
S11 A1 0.024 5.767 eV
S12 B1 0.010 5.792 eV
S13 A1 0.012 5.907 eV
S14 B2 0.000 6.015 eV
S15 B1 0.002 6.017 eV
S16 B2 0.000 6.070 eV
S17 A1 0.026 6.224 eV
S18 A2 0.000 6.369 eV
S19 B2 0.000 6.408 eV
S20 A1 0.049 6.426 eV
S21 A1 0.320 6.485 eV
S22 A2 0.000 6.497 eV
S23 A2 0.000 6.525 eV
S24 A2 0.000 6.573 eV
S25 B1 0.000 6.656 eV
S26 A1 0.001 6.766 eV
S27 B2 0.001 6.784 eV
S28 B1 0.002 6.879 eV
S29 B2 0.000 6.895 eV
S30 A1 0.000 6.908 eV
S31 B1 0.010 6.935 eV
S32 B1 0.001 7.020 eV
S33 B1 0.002 7.192 eV
S34 B2 0.000 7.205 eV
S35 A1 0.026 7.230 eV
S36 A2 0.000 7.254 eV
S37 B1 0.022 7.331 eV
S38 B2 0.000 7.386 eV
S39 B1 0.022 7.441 eV
S40 B2 0.001 7.449 eV
S41 A2 0.000 7.481 eV
S42 B1 0.010 7.515 eV
S43 A2 0.001 7.515 eV
S44 A1 0.014 7.610 eV
S45 B2 0.001 7.728 eV
S46 A1 0.065 7.773 eV
S47 A2 0.000 7.828 eV
S48 B1 0.171 7.829 eV
S49 B2 0.009 7.849 eV
S50 A2 0.000 7.886 eV
S51 A2 0.000 7.936 eV
S52 B1 0.054 7.979 eV
S53 A2 0.000 8.024 eV
S54 B1 0.135 8.030 eV
S55 A2 0.000 8.060 eV
S56 B2 0.003 8.095 eV
S57 B1 0.033 8.119 eV
S58 A2 0.000 8.119 eV
S59 B2 0.000 8.155 eV
S60 A1 0.056 8.168 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -28431.19

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:47:07

Legacy ID None

System


Full Name 2,10-Difluoropentacene

Short Name 2,10-difluoropentacene

Formula C22H12F2

Mass 314.3 u

Point Group C2v

Orientation xz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1252 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM