2,3-Difluoropentacene (C22H12F2) - excitons of #1254

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B2 0.118 2.606 eV
S2 A1 0.014 3.545 eV
S3 B2 0.000 3.834 eV
S4 B2 0.001 3.991 eV
S5 A1 0.779 4.811 eV
S6 B2 0.023 4.928 eV
S7 A1 4.639 4.942 eV
S8 B2 0.001 4.946 eV
S9 B2 0.001 5.349 eV
S10 B2 0.000 5.434 eV
S11 B2 0.008 5.797 eV
S12 B2 0.000 5.827 eV
S13 A1 0.000 5.898 eV
S14 B1 0.000 5.996 eV
S15 A1 0.003 6.023 eV
S16 B1 0.000 6.067 eV
S17 A1 0.000 6.231 eV
S18 A2 0.000 6.244 eV
S19 A2 0.000 6.371 eV
S20 B1 0.000 6.405 eV
S21 B2 0.309 6.429 eV
S22 B2 0.109 6.447 eV
S23 A2 0.000 6.472 eV
S24 B1 0.000 6.549 eV
S25 A2 0.000 6.670 eV
S26 B2 0.002 6.670 eV
S27 A1 0.000 6.769 eV
S28 A1 0.001 6.858 eV
S29 A1 0.000 6.936 eV
S30 B1 0.000 6.987 eV
S31 B2 0.008 6.991 eV
S32 A2 0.000 7.027 eV
S33 A1 0.000 7.077 eV
S34 B2 0.009 7.119 eV
S35 B1 0.000 7.176 eV
S36 B2 0.024 7.229 eV
S37 A2 0.000 7.233 eV
S38 A2 0.000 7.359 eV
S39 A1 0.058 7.387 eV
S40 B2 0.009 7.419 eV
S41 A2 0.000 7.421 eV
S42 A1 0.001 7.470 eV
S43 B1 0.000 7.557 eV
S44 A1 0.002 7.674 eV
S45 B2 0.071 7.745 eV
S46 B1 0.012 7.782 eV
S47 A2 0.000 7.814 eV
S48 B1 0.002 7.826 eV
S49 A2 0.000 7.890 eV
S50 A1 0.322 7.905 eV
S51 B1 0.000 7.906 eV
S52 B2 0.003 7.910 eV
S53 A2 0.000 7.925 eV
S54 B1 0.003 7.990 eV
S55 A2 0.000 7.991 eV
S56 B2 0.009 8.049 eV
S57 A2 0.000 8.077 eV
S58 A1 0.065 8.111 eV
S59 B1 0.001 8.121 eV
S60 A1 0.002 8.168 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -28431.00

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:47:30

Legacy ID None

System


Full Name 2,3-Difluoropentacene

Short Name 2,3-difluoropentacene

Formula C22H12F2

Mass 314.3 u

Point Group C2v

Orientation zy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1254 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM