6-Chloropentacyclo[8.8.0.02,7.03,17.013,18]octadeca-1(10),2,4,6,8,11,13(18),14,16-nonaene (C18H9Cl) - excitons of #1290

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.000 3.670 eV
S2 A' 0.085 4.132 eV
S3 A' 0.119 4.156 eV
S4 A' 0.008 4.741 eV
S5 A' 0.365 4.948 eV
S6 A' 0.128 5.239 eV
S7 A' 0.057 5.463 eV
S8 A' 0.519 5.629 eV
S9 A' 0.265 5.938 eV
S10 A' 0.478 6.197 eV
S11 A" 0.000 6.280 eV
S12 A' 0.540 6.382 eV
S13 A' 0.302 6.439 eV
S14 A" 0.000 6.498 eV
S15 A" 0.000 6.596 eV
S16 A' 0.183 6.630 eV
S17 A' 0.081 6.678 eV
S18 A" 0.000 6.790 eV
S19 A' 0.113 6.794 eV
S20 A' 0.141 6.818 eV
S21 A' 0.005 6.974 eV
S22 A" 0.000 7.025 eV
S23 A' 0.739 7.149 eV
S24 A" 0.000 7.194 eV
S25 A' 0.480 7.268 eV
S26 A' 0.073 7.291 eV
S27 A" 0.001 7.313 eV
S28 A" 0.001 7.416 eV
S29 A" 0.001 7.440 eV
S30 A' 0.463 7.473 eV
S31 A" 0.000 7.474 eV
S32 A" 0.001 7.581 eV
S33 A' 0.083 7.638 eV
S34 A" 0.000 7.694 eV
S35 A" 0.001 7.700 eV
S36 A" 0.010 7.729 eV
S37 A' 0.404 7.736 eV
S38 A" 0.001 7.908 eV
S39 A" 0.001 7.922 eV
S40 A' 0.087 7.930 eV
S41 A" 0.000 7.936 eV
S42 A' 0.161 8.005 eV
S43 A" 0.000 8.083 eV
S44 A" 0.000 8.097 eV
S45 A' 0.001 8.164 eV
S46 A" 0.001 8.193 eV
S47 A" 0.000 8.232 eV
S48 A' 0.015 8.237 eV
S49 A" 0.001 8.268 eV
S50 A" 0.001 8.331 eV
S51 A' 0.021 8.347 eV
S52 A" 0.000 8.361 eV
S53 A' 0.064 8.380 eV
S54 A" 0.000 8.382 eV
S55 A" 0.002 8.406 eV
S56 A" 0.000 8.415 eV
S57 A" 0.004 8.471 eV
S58 A' 0.051 8.480 eV
S59 A" 0.000 8.509 eV
S60 A' 0.108 8.522 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -31323.44

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:54:08

Legacy ID None

System


Full Name 6-Chloropentacyclo[8.8.0.02,7.03,17.013,18]octadeca-1(10),2,4,6,8,11,13(18),14,16-nonaene

Short Name 3-chlorobenzo[ghi]fluoranthene

Formula C18H9Cl

Mass 260.7 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1290 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM