3-Ethynylperylene (C22H12) - excitons of #1299

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.758 3.262 eV
S2 A' 0.000 4.004 eV
S3 A' 0.010 4.376 eV
S4 A' 0.003 4.385 eV
S5 A' 0.006 4.643 eV
S6 A' 0.023 4.898 eV
S7 A' 0.000 4.996 eV
S8 A' 0.014 5.127 eV
S9 A" 0.000 5.423 eV
S10 A' 0.705 5.729 eV
S11 A' 0.023 5.780 eV
S12 A' 0.112 6.041 eV
S13 A" 0.000 6.071 eV
S14 A' 0.009 6.158 eV
S15 A' 0.002 6.186 eV
S16 A' 0.150 6.270 eV
S17 A" 0.000 6.277 eV
S18 A" 0.000 6.310 eV
S19 A' 0.094 6.405 eV
S20 A" 0.000 6.497 eV
S21 A' 1.060 6.532 eV
S22 A' 0.052 6.615 eV
S23 A' 0.137 6.665 eV
S24 A" 0.000 6.743 eV
S25 A' 0.503 6.751 eV
S26 A' 0.067 6.778 eV
S27 A" 0.001 6.939 eV
S28 A' 0.070 6.950 eV
S29 A" 0.000 7.060 eV
S30 A' 0.196 7.069 eV
S31 A' 0.060 7.104 eV
S32 A' 0.166 7.148 eV
S33 A' 0.500 7.198 eV
S34 A" 0.000 7.205 eV
S35 A' 0.426 7.244 eV
S36 A" 0.005 7.253 eV
S37 A" 0.000 7.315 eV
S38 A" 0.000 7.322 eV
S39 A' 0.016 7.359 eV
S40 A' 0.661 7.366 eV
S41 A" 0.000 7.388 eV
S42 A" 0.000 7.438 eV
S43 A' 0.513 7.459 eV
S44 A" 0.000 7.536 eV
S45 A" 0.002 7.549 eV
S46 A' 0.020 7.624 eV
S47 A' 0.832 7.662 eV
S48 A" 0.001 7.673 eV
S49 A" 0.000 7.709 eV
S50 A" 0.000 7.788 eV
S51 A" 0.006 7.798 eV
S52 A' 0.237 7.837 eV
S53 A" 0.001 7.870 eV
S54 A" 0.001 7.897 eV
S55 A" 0.000 7.945 eV
S56 A' 0.006 8.012 eV
S57 A" 0.003 8.083 eV
S58 A" 0.000 8.096 eV
S59 A" 0.001 8.120 eV
S60 A" 0.000 8.134 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -22995.20

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:55:36

Legacy ID None

System


Full Name 3-Ethynylperylene

Short Name 3-ethynylperylene

Formula C22H12

Mass 276.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1299 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM