3-Methylbenzo[a]pyrene (C21H14) - excitons of #1310

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.385 3.662 eV
S2 A' 0.062 3.802 eV
S3 A' 0.006 4.604 eV
S4 A' 0.412 4.897 eV
S5 A' 0.255 4.935 eV
S6 A' 0.199 5.104 eV
S7 A' 0.195 5.284 eV
S8 A' 0.063 5.342 eV
S9 A' 1.188 5.458 eV
S10 A' 0.185 5.706 eV
S11 A' 0.083 5.965 eV
S12 A' 0.048 6.264 eV
S13 A' 0.434 6.337 eV
S14 A" 0.000 6.347 eV
S15 A' 0.051 6.455 eV
S16 A" 0.003 6.514 eV
S17 A' 0.073 6.549 eV
S18 A' 0.048 6.621 eV
S19 A" 0.000 6.689 eV
S20 A" 0.000 6.744 eV
S21 A' 0.210 6.760 eV
S22 A" 0.003 6.779 eV
S23 A' 0.685 6.832 eV
S24 A' 0.027 6.870 eV
S25 A" 0.000 7.041 eV
S26 A' 0.314 7.053 eV
S27 A" 0.001 7.091 eV
S28 A" 0.001 7.219 eV
S29 A' 0.048 7.250 eV
S30 A" 0.000 7.266 eV
S31 A' 0.432 7.341 eV
S32 A' 0.059 7.454 eV
S33 A" 0.000 7.454 eV
S34 A" 0.000 7.540 eV
S35 A' 0.046 7.572 eV
S36 A" 0.000 7.599 eV
S37 A" 0.002 7.652 eV
S38 A" 0.000 7.679 eV
S39 A' 0.143 7.722 eV
S40 A" 0.003 7.723 eV
S41 A" 0.000 7.768 eV
S42 A' 0.084 7.803 eV
S43 A" 0.000 7.810 eV
S44 A" 0.001 7.825 eV
S45 A" 0.000 7.866 eV
S46 A' 0.558 7.866 eV
S47 A" 0.000 8.001 eV
S48 A' 0.105 8.007 eV
S49 A" 0.002 8.034 eV
S50 A' 0.212 8.036 eV
S51 A" 0.000 8.071 eV
S52 A' 0.004 8.087 eV
S53 A" 0.002 8.105 eV
S54 A' 0.020 8.199 eV
S55 A" 0.003 8.235 eV
S56 A" 0.000 8.248 eV
S57 A' 0.471 8.277 eV
S58 A" 0.000 8.331 eV
S59 A" 0.000 8.340 eV
S60 A' 0.062 8.360 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21993.07

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:57:25

Legacy ID None

System


Full Name 3-Methylbenzo[a]pyrene

Short Name 3-methylbenzo(a)pyrene

Formula C21H14

Mass 266.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1310 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM