13-Methylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C21H14) - excitons of #1311

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.011 3.994 eV
S2 A' 0.061 4.118 eV
S3 A' 0.323 4.160 eV
S4 A' 0.120 4.830 eV
S5 A' 0.193 5.102 eV
S6 A' 0.368 5.172 eV
S7 A' 0.694 5.477 eV
S8 A' 0.081 5.685 eV
S9 A' 0.352 5.744 eV
S10 A' 1.012 5.950 eV
S11 A' 0.144 6.169 eV
S12 A' 0.077 6.281 eV
S13 A' 0.323 6.405 eV
S14 A" 0.000 6.490 eV
S15 A' 0.139 6.515 eV
S16 A' 0.024 6.587 eV
S17 A" 0.001 6.667 eV
S18 A' 0.034 6.679 eV
S19 A' 0.098 6.732 eV
S20 A' 0.265 6.821 eV
S21 A' 0.062 6.872 eV
S22 A' 0.394 7.121 eV
S23 A" 0.000 7.148 eV
S24 A" 0.002 7.160 eV
S25 A" 0.000 7.170 eV
S26 A" 0.001 7.212 eV
S27 A' 0.160 7.256 eV
S28 A" 0.000 7.322 eV
S29 A' 0.019 7.353 eV
S30 A" 0.001 7.372 eV
S31 A" 0.008 7.416 eV
S32 A" 0.001 7.458 eV
S33 A' 0.037 7.477 eV
S34 A" 0.000 7.503 eV
S35 A' 0.137 7.572 eV
S36 A" 0.000 7.581 eV
S37 A' 0.391 7.598 eV
S38 A" 0.004 7.689 eV
S39 A" 0.000 7.695 eV
S40 A" 0.001 7.736 eV
S41 A" 0.001 7.745 eV
S42 A' 0.080 7.746 eV
S43 A" 0.000 7.782 eV
S44 A' 0.122 7.817 eV
S45 A' 0.055 7.906 eV
S46 A" 0.000 7.929 eV
S47 A" 0.000 7.963 eV
S48 A" 0.000 8.051 eV
S49 A' 0.134 8.068 eV
S50 A" 0.001 8.071 eV
S51 A" 0.000 8.105 eV
S52 A" 0.001 8.112 eV
S53 A" 0.000 8.162 eV
S54 A' 0.215 8.202 eV
S55 A" 0.000 8.264 eV
S56 A' 0.059 8.273 eV
S57 A" 0.000 8.319 eV
S58 A" 0.008 8.367 eV
S59 A' 0.054 8.383 eV
S60 A" 0.000 8.401 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21992.70

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:57:39

Legacy ID None

System


Full Name 13-Methylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name 3-methylbenzo(b)fluoranthene

Formula C21H14

Mass 266.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1311 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM