3-Methylbenzo[e]pyrene (C21H14) - excitons of #1312

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.005 4.034 eV
S2 A' 0.250 4.214 eV
S3 A' 0.069 4.691 eV
S4 A' 0.028 4.875 eV
S5 A' 0.701 4.989 eV
S6 A' 0.039 5.112 eV
S7 A' 0.365 5.466 eV
S8 A' 0.044 5.530 eV
S9 A' 0.240 5.560 eV
S10 A' 0.043 5.764 eV
S11 A' 0.077 5.937 eV
S12 A' 0.382 5.959 eV
S13 A' 0.343 6.394 eV
S14 A' 0.088 6.511 eV
S15 A' 0.094 6.589 eV
S16 A' 0.116 6.715 eV
S17 A" 0.000 6.725 eV
S18 A" 0.004 6.773 eV
S19 A' 0.599 6.788 eV
S20 A" 0.000 6.800 eV
S21 A' 0.835 6.939 eV
S22 A' 0.004 6.997 eV
S23 A" 0.000 7.028 eV
S24 A' 0.176 7.073 eV
S25 A" 0.000 7.087 eV
S26 A" 0.000 7.190 eV
S27 A' 0.198 7.220 eV
S28 A" 0.001 7.243 eV
S29 A' 0.848 7.251 eV
S30 A' 0.112 7.305 eV
S31 A" 0.002 7.364 eV
S32 A" 0.003 7.492 eV
S33 A" 0.006 7.524 eV
S34 A" 0.000 7.548 eV
S35 A' 0.040 7.549 eV
S36 A' 0.047 7.590 eV
S37 A" 0.000 7.607 eV
S38 A" 0.000 7.646 eV
S39 A" 0.001 7.676 eV
S40 A" 0.003 7.713 eV
S41 A" 0.000 7.716 eV
S42 A' 0.134 7.729 eV
S43 A' 0.126 7.830 eV
S44 A' 0.104 7.858 eV
S45 A" 0.000 7.864 eV
S46 A' 0.014 7.915 eV
S47 A" 0.000 7.939 eV
S48 A" 0.001 7.978 eV
S49 A" 0.001 8.013 eV
S50 A" 0.000 8.022 eV
S51 A' 0.028 8.135 eV
S52 A" 0.001 8.142 eV
S53 A' 0.322 8.154 eV
S54 A' 0.219 8.225 eV
S55 A" 0.002 8.273 eV
S56 A" 0.000 8.287 eV
S57 A' 0.040 8.297 eV
S58 A" 0.000 8.322 eV
S59 A" 0.000 8.334 eV
S60 A" 0.003 8.477 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21993.10

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 19:57:53

Legacy ID None

System


Full Name 3-Methylbenzo[e]pyrene

Short Name 3-methylbenzo[e]pyrene

Formula C21H14

Mass 266.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1312 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM