4-Phenylazulene (C16H12) - excitons of #1354

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.022 2.576 eV
S2 A' 0.004 3.908 eV
S3 A' 0.122 4.996 eV
S4 A" 0.000 5.088 eV
S5 A" 0.000 5.349 eV
S6 A' 0.038 5.509 eV
S7 A' 0.033 5.527 eV
S8 A" 0.000 5.642 eV
S9 A' 1.578 5.670 eV
S10 A" 0.002 6.014 eV
S11 A" 0.000 6.123 eV
S12 A' 0.072 6.323 eV
S13 A' 0.784 6.413 eV
S14 A" 0.000 6.444 eV
S15 A" 0.000 6.492 eV
S16 A' 0.018 6.539 eV
S17 A' 0.002 6.618 eV
S18 A" 0.002 6.814 eV
S19 A' 0.069 6.843 eV
S20 A" 0.003 6.956 eV
S21 A" 0.000 7.006 eV
S22 A" 0.002 7.059 eV
S23 A" 0.000 7.216 eV
S24 A' 0.943 7.309 eV
S25 A" 0.011 7.360 eV
S26 A" 0.000 7.462 eV
S27 A' 0.162 7.554 eV
S28 A" 0.394 7.617 eV
S29 A" 0.059 7.719 eV
S30 A" 0.011 7.774 eV
S31 A' 0.524 7.787 eV
S32 A" 0.097 7.796 eV
S33 A' 0.002 7.875 eV
S34 A" 0.034 7.876 eV
S35 A" 0.018 7.903 eV
S36 A' 0.013 7.915 eV
S37 A' 0.015 7.949 eV
S38 A" 0.002 7.957 eV
S39 A" 0.030 7.973 eV
S40 A" 0.007 8.031 eV
S41 A' 0.048 8.040 eV
S42 A" 0.025 8.045 eV
S43 A" 0.002 8.110 eV
S44 A' 0.030 8.120 eV
S45 A" 0.005 8.134 eV
S46 A' 0.048 8.187 eV
S47 A" 0.002 8.254 eV
S48 A' 0.106 8.255 eV
S49 A" 0.011 8.285 eV
S50 A" 0.004 8.303 eV
S51 A' 0.051 8.478 eV
S52 A" 0.000 8.483 eV
S53 A' 0.003 8.544 eV
S54 A" 0.008 8.556 eV
S55 A" 0.011 8.582 eV
S56 A' 0.042 8.608 eV
S57 A" 0.000 8.621 eV
S58 A' 0.122 8.646 eV
S59 A" 0.000 8.678 eV
S60 A' 0.016 8.701 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -16773.66

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:05:27

Legacy ID None

System


Full Name 4-Phenylazulene

Short Name 4-phenylazulene

Formula C16H12

Mass 204.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1354 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM