Pentacyclo[14.2.1.05,18.06,11.012,17]nonadeca-1(18),2,4,6,8,10,12,14,16-nonaene (C19H12) - excitons of #1357

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A1 0.007 4.389 eV
S2 B1 0.000 4.610 eV
S3 B1 0.003 4.901 eV
S4 A1 0.049 4.937 eV
S5 A1 1.109 5.533 eV
S6 B1 1.024 5.543 eV
S7 A1 0.035 5.748 eV
S8 B1 0.040 5.790 eV
S9 B1 0.050 6.105 eV
S10 A1 0.189 6.397 eV
S11 B1 0.003 6.461 eV
S12 A1 0.000 6.470 eV
S13 B1 0.001 6.602 eV
S14 B1 0.146 6.858 eV
S15 A1 0.001 6.865 eV
S16 A1 0.684 7.013 eV
S17 B1 0.199 7.118 eV
S18 A2 0.000 7.194 eV
S19 A2 0.000 7.212 eV
S20 B1 0.103 7.276 eV
S21 B2 0.004 7.277 eV
S22 B2 0.000 7.299 eV
S23 B2 0.001 7.329 eV
S24 A2 0.000 7.342 eV
S25 B2 0.011 7.361 eV
S26 A1 0.008 7.376 eV
S27 A2 0.000 7.392 eV
S28 A1 0.261 7.427 eV
S29 A2 0.000 7.456 eV
S30 B1 0.451 7.461 eV
S31 B2 0.002 7.465 eV
S32 A2 0.000 7.558 eV
S33 B2 0.000 7.571 eV
S34 B1 0.126 7.605 eV
S35 A1 0.019 7.612 eV
S36 A2 0.000 7.691 eV
S37 B2 0.002 7.783 eV
S38 A1 0.278 7.828 eV
S39 B1 0.291 7.898 eV
S40 B2 0.000 8.002 eV
S41 A2 0.000 8.002 eV
S42 A1 0.446 8.033 eV
S43 B2 0.000 8.046 eV
S44 A2 0.000 8.050 eV
S45 B2 0.003 8.071 eV
S46 A2 0.000 8.086 eV
S47 B2 0.002 8.172 eV
S48 A1 0.023 8.268 eV
S49 B2 0.001 8.273 eV
S50 B1 0.149 8.273 eV
S51 A2 0.000 8.288 eV
S52 A2 0.000 8.298 eV
S53 A2 0.000 8.344 eV
S54 A2 0.000 8.478 eV
S55 B2 0.000 8.506 eV
S56 A2 0.000 8.571 eV
S57 B2 0.000 8.598 eV
S58 A2 0.000 8.717 eV
S59 B2 0.001 8.745 eV
S60 A2 0.000 8.749 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -19886.10

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:05:53

Legacy ID None

System


Full Name Pentacyclo[14.2.1.05,18.06,11.012,17]nonadeca-1(18),2,4,6,8,10,12,14,16-nonaene

Short Name 4h-cyclopenta[def]triphenylene

Formula C19H12

Mass 240.3 u

Point Group C2v

Orientation zx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1357 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM