5-Methylbenzo[a]pyrene (C21H14) - excitons of #1363

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.336 3.737 eV
S2 A' 0.064 3.840 eV
S3 A' 0.026 4.674 eV
S4 A' 0.012 4.893 eV
S5 A' 0.602 5.023 eV
S6 A' 0.204 5.167 eV
S7 A' 0.257 5.233 eV
S8 A' 0.143 5.369 eV
S9 A' 1.095 5.472 eV
S10 A' 0.088 5.712 eV
S11 A' 0.072 5.970 eV
S12 A' 0.099 6.330 eV
S13 A' 0.365 6.360 eV
S14 A" 0.000 6.380 eV
S15 A' 0.016 6.441 eV
S16 A" 0.002 6.481 eV
S17 A' 0.020 6.532 eV
S18 A' 0.037 6.644 eV
S19 A" 0.000 6.682 eV
S20 A" 0.000 6.747 eV
S21 A' 0.228 6.764 eV
S22 A' 0.658 6.803 eV
S23 A" 0.001 6.870 eV
S24 A' 0.007 6.891 eV
S25 A' 0.360 7.075 eV
S26 A" 0.000 7.138 eV
S27 A" 0.002 7.171 eV
S28 A" 0.001 7.265 eV
S29 A' 0.014 7.273 eV
S30 A" 0.000 7.300 eV
S31 A' 0.729 7.303 eV
S32 A" 0.000 7.442 eV
S33 A' 0.184 7.497 eV
S34 A" 0.000 7.575 eV
S35 A" 0.000 7.585 eV
S36 A' 0.041 7.617 eV
S37 A" 0.004 7.677 eV
S38 A' 0.171 7.688 eV
S39 A" 0.000 7.716 eV
S40 A" 0.000 7.724 eV
S41 A' 0.104 7.799 eV
S42 A" 0.003 7.840 eV
S43 A' 0.233 7.848 eV
S44 A" 0.000 7.848 eV
S45 A" 0.001 7.875 eV
S46 A" 0.001 7.926 eV
S47 A' 0.295 7.928 eV
S48 A" 0.000 7.975 eV
S49 A' 0.221 8.021 eV
S50 A" 0.000 8.078 eV
S51 A' 0.153 8.102 eV
S52 A" 0.003 8.115 eV
S53 A" 0.000 8.151 eV
S54 A' 0.028 8.180 eV
S55 A" 0.001 8.246 eV
S56 A" 0.001 8.294 eV
S57 A" 0.001 8.302 eV
S58 A" 0.002 8.328 eV
S59 A' 0.203 8.353 eV
S60 A" 0.007 8.395 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21993.08

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:07:00

Legacy ID None

System


Full Name 5-Methylbenzo[a]pyrene

Short Name 5-methylbenzo(a)pyrene

Formula C21H14

Mass 266.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1363 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM