18,19-Dimethylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C22H16) - excitons of #1374

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.014 3.907 eV
S2 A' 0.299 4.128 eV
S3 A' 0.033 4.192 eV
S4 A' 0.338 4.729 eV
S5 A' 0.208 5.077 eV
S6 A' 0.347 5.211 eV
S7 A' 0.785 5.483 eV
S8 A' 0.181 5.650 eV
S9 A' 0.316 5.727 eV
S10 A' 0.833 5.932 eV
S11 A' 0.069 6.175 eV
S12 A' 0.127 6.236 eV
S13 A' 0.036 6.416 eV
S14 A' 0.388 6.473 eV
S15 A" 0.000 6.535 eV
S16 A' 0.077 6.578 eV
S17 A' 0.046 6.617 eV
S18 A' 0.251 6.679 eV
S19 A" 0.000 6.717 eV
S20 A' 0.008 6.794 eV
S21 A' 0.311 6.869 eV
S22 A" 0.004 6.920 eV
S23 A' 0.470 7.088 eV
S24 A" 0.000 7.095 eV
S25 A" 0.001 7.166 eV
S26 A" 0.001 7.215 eV
S27 A" 0.000 7.238 eV
S28 A" 0.001 7.293 eV
S29 A' 0.080 7.316 eV
S30 A" 0.002 7.349 eV
S31 A" 0.000 7.372 eV
S32 A' 0.071 7.386 eV
S33 A' 0.030 7.409 eV
S34 A" 0.000 7.481 eV
S35 A' 0.121 7.494 eV
S36 A" 0.002 7.551 eV
S37 A" 0.004 7.617 eV
S38 A' 0.132 7.634 eV
S39 A" 0.000 7.667 eV
S40 A" 0.002 7.694 eV
S41 A" 0.002 7.707 eV
S42 A' 0.161 7.734 eV
S43 A" 0.001 7.753 eV
S44 A" 0.000 7.770 eV
S45 A' 0.026 7.827 eV
S46 A' 0.173 7.902 eV
S47 A" 0.000 7.903 eV
S48 A" 0.001 7.946 eV
S49 A' 0.166 8.036 eV
S50 A" 0.000 8.060 eV
S51 A" 0.001 8.069 eV
S52 A" 0.000 8.107 eV
S53 A' 0.273 8.148 eV
S54 A" 0.000 8.211 eV
S55 A' 0.010 8.244 eV
S56 A" 0.001 8.254 eV
S57 A" 0.000 8.278 eV
S58 A' 0.059 8.284 eV
S59 A" 0.006 8.291 eV
S60 A" 0.001 8.304 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -23062.36

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:09:14

Legacy ID None

System


Full Name 18,19-Dimethylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name 5,6-dimethylbenzo(b)fluoranthene

Formula C22H16

Mass 280.4 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1374 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM