7-Methylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C21H14) - excitons of #1422

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.040 4.036 eV
S2 0.200 4.182 eV
S3 0.108 4.212 eV
S4 0.137 4.777 eV
S5 0.239 5.033 eV
S6 0.407 5.194 eV
S7 0.628 5.500 eV
S8 0.107 5.678 eV
S9 0.432 5.750 eV
S10 0.780 5.964 eV
S11 0.262 6.203 eV
S12 0.016 6.234 eV
S13 0.161 6.385 eV
S14 0.002 6.504 eV
S15 0.138 6.569 eV
S16 0.058 6.592 eV
S17 0.001 6.663 eV
S18 0.088 6.684 eV
S19 0.138 6.730 eV
S20 0.156 6.814 eV
S21 0.119 6.867 eV
S22 0.005 7.032 eV
S23 0.223 7.099 eV
S24 0.006 7.123 eV
S25 0.002 7.147 eV
S26 0.048 7.281 eV
S27 0.016 7.282 eV
S28 0.113 7.311 eV
S29 0.001 7.322 eV
S30 0.004 7.396 eV
S31 0.005 7.417 eV
S32 0.004 7.476 eV
S33 0.000 7.478 eV
S34 0.001 7.525 eV
S35 0.115 7.565 eV
S36 0.027 7.592 eV
S37 0.469 7.597 eV
S38 0.012 7.656 eV
S39 0.000 7.741 eV
S40 0.003 7.744 eV
S41 0.035 7.763 eV
S42 0.001 7.784 eV
S43 0.072 7.866 eV
S44 0.004 7.886 eV
S45 0.029 7.943 eV
S46 0.091 7.953 eV
S47 0.003 8.000 eV
S48 0.103 8.036 eV
S49 0.001 8.066 eV
S50 0.000 8.072 eV
S51 0.000 8.113 eV
S52 0.001 8.154 eV
S53 0.317 8.186 eV
S54 0.004 8.248 eV
S55 0.221 8.276 eV
S56 0.010 8.304 eV
S57 0.000 8.328 eV
S58 0.067 8.359 eV
S59 0.009 8.390 eV
S60 0.003 8.410 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21992.58

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:19:55

Legacy ID None

System


Full Name 7-Methylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name 8-methylbenzo(b)fluoranthene

Formula C21H14

Mass 266.3 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1422 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM