6-Methylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C21H14) - excitons of #1435

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.014 3.981 eV
S2 A' 0.315 4.079 eV
S3 A' 0.073 4.168 eV
S4 A' 0.160 4.755 eV
S5 A' 0.226 5.062 eV
S6 A' 0.364 5.219 eV
S7 A' 0.555 5.463 eV
S8 A' 0.064 5.593 eV
S9 A' 0.510 5.739 eV
S10 A' 0.743 5.981 eV
S11 A' 0.170 6.182 eV
S12 A' 0.083 6.281 eV
S13 A' 0.278 6.406 eV
S14 A" 0.000 6.440 eV
S15 A' 0.079 6.585 eV
S16 A' 0.058 6.593 eV
S17 A' 0.034 6.611 eV
S18 A" 0.001 6.665 eV
S19 A' 0.104 6.723 eV
S20 A' 0.323 6.852 eV
S21 A' 0.145 6.896 eV
S22 A" 0.003 6.910 eV
S23 A" 0.001 7.115 eV
S24 A' 0.395 7.119 eV
S25 A" 0.001 7.179 eV
S26 A" 0.003 7.285 eV
S27 A" 0.000 7.306 eV
S28 A" 0.000 7.321 eV
S29 A' 0.037 7.334 eV
S30 A' 0.028 7.370 eV
S31 A" 0.004 7.432 eV
S32 A" 0.000 7.466 eV
S33 A" 0.001 7.510 eV
S34 A' 0.010 7.518 eV
S35 A' 0.424 7.572 eV
S36 A' 0.062 7.626 eV
S37 A" 0.000 7.636 eV
S38 A" 0.002 7.687 eV
S39 A" 0.001 7.717 eV
S40 A" 0.001 7.742 eV
S41 A" 0.002 7.754 eV
S42 A' 0.083 7.776 eV
S43 A" 0.002 7.887 eV
S44 A" 0.000 7.908 eV
S45 A" 0.002 7.933 eV
S46 A' 0.211 7.936 eV
S47 A' 0.153 7.950 eV
S48 A" 0.001 8.007 eV
S49 A" 0.001 8.054 eV
S50 A' 0.157 8.060 eV
S51 A" 0.000 8.118 eV
S52 A" 0.000 8.138 eV
S53 A' 0.203 8.154 eV
S54 A" 0.003 8.209 eV
S55 A" 0.000 8.239 eV
S56 A' 0.064 8.279 eV
S57 A' 0.138 8.322 eV
S58 A" 0.000 8.330 eV
S59 A" 0.003 8.376 eV
S60 A" 0.002 8.431 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21992.62

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:22:42

Legacy ID None

System


Full Name 6-Methylpentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name 9-methylbenzo(b)fluoranthene

Formula C21H14

Mass 266.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1435 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM