9-Methylbenzo[k]fluoranthene (C21H14) - excitons of #1436

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.293 3.827 eV
S2 A' 0.001 4.002 eV
S3 A' 0.035 4.507 eV
S4 A' 0.108 4.611 eV
S5 A' 0.692 4.678 eV
S6 A' 0.892 5.325 eV
S7 A' 0.003 5.558 eV
S8 A' 0.026 5.578 eV
S9 A' 0.379 5.822 eV
S10 A' 0.103 5.939 eV
S11 A' 0.318 6.108 eV
S12 A' 1.340 6.204 eV
S13 A' 0.058 6.262 eV
S14 A' 0.074 6.439 eV
S15 A" 0.000 6.607 eV
S16 A' 0.135 6.620 eV
S17 A" 0.000 6.644 eV
S18 A' 0.103 6.653 eV
S19 A' 0.439 6.783 eV
S20 A" 0.000 6.895 eV
S21 A' 0.010 6.896 eV
S22 A" 0.000 6.944 eV
S23 A' 0.003 6.947 eV
S24 A" 0.000 7.002 eV
S25 A' 0.042 7.044 eV
S26 A" 0.000 7.073 eV
S27 A' 0.020 7.112 eV
S28 A" 0.000 7.178 eV
S29 A" 0.000 7.322 eV
S30 A' 0.038 7.391 eV
S31 A" 0.000 7.413 eV
S32 A" 0.005 7.414 eV
S33 A" 0.001 7.455 eV
S34 A" 0.000 7.567 eV
S35 A' 0.249 7.583 eV
S36 A' 0.096 7.653 eV
S37 A" 0.000 7.694 eV
S38 A" 0.003 7.713 eV
S39 A" 0.001 7.778 eV
S40 A' 0.742 7.787 eV
S41 A" 0.000 7.790 eV
S42 A" 0.001 7.869 eV
S43 A' 0.007 7.905 eV
S44 A' 0.002 7.913 eV
S45 A" 0.000 7.925 eV
S46 A" 0.001 7.950 eV
S47 A" 0.001 7.980 eV
S48 A" 0.000 8.038 eV
S49 A' 0.066 8.053 eV
S50 A' 0.049 8.089 eV
S51 A" 0.002 8.112 eV
S52 A" 0.005 8.138 eV
S53 A" 0.001 8.177 eV
S54 A' 0.011 8.182 eV
S55 A" 0.000 8.226 eV
S56 A' 0.001 8.245 eV
S57 A" 0.001 8.272 eV
S58 A" 0.000 8.298 eV
S59 A' 0.037 8.344 eV
S60 A' 0.003 8.383 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21992.62

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:22:56

Legacy ID None

System


Full Name 9-Methylbenzo[k]fluoranthene

Short Name 9-methylbenzo[k]fluoranthene

Formula C21H14

Mass 266.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1436 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM