Pentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C20H12) - excitons of #1445

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.013 4.009 eV
S2 A' 0.269 4.158 eV
S3 A' 0.067 4.202 eV
S4 A' 0.196 4.804 eV
S5 A' 0.219 5.099 eV
S6 A' 0.368 5.223 eV
S7 A' 0.648 5.520 eV
S8 A' 0.038 5.701 eV
S9 A' 0.383 5.760 eV
S10 A' 0.978 6.002 eV
S11 A' 0.039 6.195 eV
S12 A' 0.116 6.311 eV
S13 A' 0.237 6.443 eV
S14 A" 0.000 6.522 eV
S15 A' 0.178 6.569 eV
S16 A' 0.151 6.630 eV
S17 A' 0.002 6.688 eV
S18 A" 0.000 6.711 eV
S19 A' 0.133 6.761 eV
S20 A' 0.178 6.861 eV
S21 A' 0.126 6.929 eV
S22 A' 0.439 7.150 eV
S23 A" 0.000 7.158 eV
S24 A" 0.000 7.178 eV
S25 A" 0.001 7.213 eV
S26 A" 0.001 7.323 eV
S27 A" 0.001 7.351 eV
S28 A' 0.083 7.352 eV
S29 A" 0.000 7.384 eV
S30 A' 0.026 7.421 eV
S31 A" 0.006 7.472 eV
S32 A" 0.000 7.489 eV
S33 A' 0.035 7.517 eV
S34 A" 0.000 7.597 eV
S35 A' 0.174 7.638 eV
S36 A' 0.261 7.672 eV
S37 A" 0.000 7.697 eV
S38 A" 0.004 7.701 eV
S39 A" 0.001 7.761 eV
S40 A" 0.001 7.780 eV
S41 A' 0.042 7.805 eV
S42 A" 0.000 7.906 eV
S43 A" 0.000 7.909 eV
S44 A' 0.250 7.923 eV
S45 A' 0.058 7.967 eV
S46 A" 0.001 8.028 eV
S47 A" 0.001 8.082 eV
S48 A" 0.000 8.115 eV
S49 A" 0.000 8.121 eV
S50 A' 0.164 8.135 eV
S51 A" 0.000 8.210 eV
S52 A' 0.261 8.234 eV
S53 A" 0.001 8.261 eV
S54 A" 0.002 8.269 eV
S55 A' 0.014 8.324 eV
S56 A" 0.002 8.345 eV
S57 A' 0.099 8.400 eV
S58 A" 0.002 8.411 eV
S59 A" 0.002 8.449 eV
S60 A" 0.000 8.477 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -20923.04

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:24:41

Legacy ID None

System


Full Name Pentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name Benzo(B)Fluoranthene

Formula C20H12

Mass 252.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1445 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM