Pentacyclo[12.8.0.02,7.08,13.015,20]docosa-1(14),2,4,6,8,10,12,15,17,19,21-undecaene (C22H14) - excitons of #1449

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.003 4.104 eV
S2 0.093 4.208 eV
S3 0.007 4.528 eV
S4 0.517 4.973 eV
S5 0.696 5.025 eV
S6 0.301 5.155 eV
S7 0.017 5.245 eV
S8 0.945 5.515 eV
S9 0.047 5.557 eV
S10 0.047 5.718 eV
S11 0.178 5.783 eV
S12 0.011 5.945 eV
S13 0.012 6.062 eV
S14 0.004 6.251 eV
S15 0.023 6.343 eV
S16 0.024 6.407 eV
S17 0.007 6.543 eV
S18 0.270 6.675 eV
S19 0.024 6.709 eV
S20 0.089 6.794 eV
S21 0.434 6.815 eV
S22 0.260 6.872 eV
S23 0.133 6.938 eV
S24 0.033 6.954 eV
S25 0.019 7.017 eV
S26 0.026 7.081 eV
S27 0.106 7.096 eV
S28 0.087 7.136 eV
S29 0.047 7.197 eV
S30 0.084 7.206 eV
S31 0.193 7.238 eV
S32 0.008 7.264 eV
S33 0.027 7.340 eV
S34 0.025 7.345 eV
S35 0.008 7.373 eV
S36 0.040 7.447 eV
S37 0.047 7.458 eV
S38 0.343 7.487 eV
S39 0.303 7.522 eV
S40 0.042 7.561 eV
S41 0.006 7.569 eV
S42 0.072 7.601 eV
S43 0.019 7.620 eV
S44 0.029 7.657 eV
S45 0.118 7.688 eV
S46 0.007 7.711 eV
S47 0.014 7.744 eV
S48 0.133 7.757 eV
S49 0.066 7.844 eV
S50 0.125 7.896 eV
S51 0.017 7.913 eV
S52 0.066 7.962 eV
S53 0.006 7.988 eV
S54 0.049 8.021 eV
S55 0.020 8.072 eV
S56 0.016 8.088 eV
S57 0.166 8.106 eV
S58 0.235 8.117 eV
S59 0.033 8.137 eV
S60 0.058 8.171 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -23029.45

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:25:30

Legacy ID None

System


Full Name Pentacyclo[12.8.0.02,7.08,13.015,20]docosa-1(14),2,4,6,8,10,12,15,17,19,21-undecaene

Short Name Benzo(G)chrysene

Formula C22H14

Mass 278.4 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1449 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM