19-Fluoropentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C20H11F) - excitons of #1453

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.011 4.012 eV
S2 A' 0.232 4.113 eV
S3 A' 0.071 4.257 eV
S4 A' 0.260 4.751 eV
S5 A' 0.191 5.091 eV
S6 A' 0.370 5.220 eV
S7 A' 0.662 5.487 eV
S8 A' 0.112 5.686 eV
S9 A' 0.255 5.756 eV
S10 A' 0.918 5.991 eV
S11 A' 0.046 6.169 eV
S12 A' 0.159 6.292 eV
S13 A' 0.337 6.438 eV
S14 A" 0.000 6.567 eV
S15 A' 0.080 6.569 eV
S16 A' 0.166 6.642 eV
S17 A' 0.012 6.721 eV
S18 A" 0.001 6.736 eV
S19 A' 0.095 6.782 eV
S20 A' 0.209 6.884 eV
S21 A' 0.201 6.966 eV
S22 A" 0.000 7.135 eV
S23 A' 0.411 7.164 eV
S24 A" 0.000 7.208 eV
S25 A' 0.048 7.321 eV
S26 A" 0.002 7.329 eV
S27 A" 0.001 7.376 eV
S28 A' 0.023 7.391 eV
S29 A" 0.000 7.416 eV
S30 A" 0.001 7.438 eV
S31 A' 0.066 7.534 eV
S32 A" 0.001 7.555 eV
S33 A" 0.000 7.602 eV
S34 A' 0.107 7.622 eV
S35 A' 0.152 7.650 eV
S36 A" 0.001 7.682 eV
S37 A" 0.001 7.755 eV
S38 A' 0.039 7.766 eV
S39 A" 0.001 7.781 eV
S40 A" 0.001 7.840 eV
S41 A" 0.003 7.860 eV
S42 A" 0.000 7.934 eV
S43 A' 0.213 7.936 eV
S44 A' 0.295 7.965 eV
S45 A" 0.001 7.970 eV
S46 A" 0.000 8.032 eV
S47 A' 0.028 8.116 eV
S48 A" 0.001 8.183 eV
S49 A" 0.001 8.189 eV
S50 A' 0.201 8.221 eV
S51 A" 0.006 8.225 eV
S52 A" 0.001 8.274 eV
S53 A' 0.165 8.289 eV
S54 A" 0.000 8.297 eV
S55 A" 0.003 8.340 eV
S56 A" 0.001 8.365 eV
S57 A" 0.001 8.376 eV
S58 A' 0.060 8.437 eV
S59 A' 0.022 8.468 eV
S60 A" 0.000 8.483 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -23624.18

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:26:21

Legacy ID None

System


Full Name 19-Fluoropentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name CID10015957

Formula C20H11F

Mass 270.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1453 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM