7-Fluoro-6-thiapentacyclo[11.8.0.03,11.05,9.015,20]henicosa-1(21),2,4,7,9,11,13,15,17,19-decaene (C20H11FS) - excitons of #1455

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.117 2.873 eV
S2 A' 0.002 3.648 eV
S3 A' 0.020 4.058 eV
S4 A' 0.014 4.360 eV
S5 A" 0.000 4.692 eV
S6 A' 2.193 4.930 eV
S7 A' 2.086 5.028 eV
S8 A' 0.512 5.099 eV
S9 A' 0.018 5.251 eV
S10 A' 0.008 5.498 eV
S11 A' 0.171 5.778 eV
S12 A' 0.020 5.876 eV
S13 A' 0.002 5.961 eV
S14 A' 0.057 6.088 eV
S15 A" 0.000 6.118 eV
S16 A" 0.000 6.168 eV
S17 A' 0.013 6.206 eV
S18 A" 0.000 6.228 eV
S19 A" 0.000 6.320 eV
S20 A' 0.234 6.406 eV
S21 A' 0.064 6.505 eV
S22 A" 0.000 6.507 eV
S23 A" 0.000 6.522 eV
S24 A" 0.000 6.606 eV
S25 A' 0.021 6.610 eV
S26 A" 0.000 6.679 eV
S27 A" 0.000 6.712 eV
S28 A" 0.000 6.772 eV
S29 A' 0.037 6.854 eV
S30 A' 0.013 6.901 eV
S31 A' 0.004 6.943 eV
S32 A' 0.013 6.993 eV
S33 A' 0.030 7.095 eV
S34 A" 0.000 7.147 eV
S35 A" 0.000 7.191 eV
S36 A" 0.000 7.218 eV
S37 A' 0.015 7.251 eV
S38 A' 0.004 7.294 eV
S39 A' 0.090 7.345 eV
S40 A" 0.000 7.451 eV
S41 A' 0.027 7.483 eV
S42 A" 0.000 7.510 eV
S43 A' 0.025 7.629 eV
S44 A" 0.002 7.634 eV
S45 A" 0.002 7.652 eV
S46 A' 0.096 7.693 eV
S47 A" 0.003 7.732 eV
S48 A' 0.019 7.784 eV
S49 A" 0.000 7.853 eV
S50 A" 0.001 7.867 eV
S51 A" 0.000 7.884 eV
S52 A" 0.000 7.908 eV
S53 A' 0.028 7.946 eV
S54 A' 0.003 7.962 eV
S55 A" 0.001 7.993 eV
S56 A" 0.000 8.010 eV
S57 A' 0.044 8.133 eV
S58 A" 0.015 8.133 eV
S59 A" 0.001 8.177 eV
S60 A" 0.001 8.190 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -34459.62

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:26:50

Legacy ID None

System


Full Name 7-Fluoro-6-thiapentacyclo[11.8.0.03,11.05,9.015,20]henicosa-1(21),2,4,7,9,11,13,15,17,19-decaene

Short Name CID101464261

Formula C20H11FS

Mass 302.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1455 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM