1-Fluoropentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene (C20H11F) - excitons of #1459

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.005 3.960 eV
S2 A' 0.082 4.151 eV
S3 A' 0.264 4.204 eV
S4 A' 0.212 4.840 eV
S5 A' 0.274 5.071 eV
S6 A' 0.359 5.196 eV
S7 A' 0.400 5.551 eV
S8 A' 0.333 5.676 eV
S9 A' 0.285 5.836 eV
S10 A' 0.937 5.996 eV
S11 A' 0.012 6.134 eV
S12 A' 0.112 6.285 eV
S13 A' 0.368 6.459 eV
S14 A' 0.065 6.476 eV
S15 A" 0.000 6.518 eV
S16 A' 0.032 6.620 eV
S17 A' 0.195 6.635 eV
S18 A" 0.000 6.734 eV
S19 A' 0.089 6.793 eV
S20 A' 0.080 6.883 eV
S21 A' 0.058 6.975 eV
S22 A' 0.585 7.159 eV
S23 A" 0.000 7.168 eV
S24 A" 0.000 7.268 eV
S25 A" 0.001 7.288 eV
S26 A" 0.000 7.332 eV
S27 A' 0.046 7.373 eV
S28 A' 0.116 7.454 eV
S29 A" 0.002 7.481 eV
S30 A" 0.005 7.490 eV
S31 A" 0.001 7.503 eV
S32 A' 0.001 7.518 eV
S33 A" 0.000 7.577 eV
S34 A' 0.019 7.617 eV
S35 A" 0.002 7.633 eV
S36 A' 0.478 7.668 eV
S37 A" 0.003 7.729 eV
S38 A" 0.000 7.739 eV
S39 A' 0.051 7.757 eV
S40 A" 0.000 7.833 eV
S41 A" 0.000 7.863 eV
S42 A' 0.242 7.891 eV
S43 A" 0.000 7.915 eV
S44 A' 0.036 8.001 eV
S45 A" 0.000 8.052 eV
S46 A" 0.000 8.080 eV
S47 A' 0.300 8.107 eV
S48 A" 0.000 8.129 eV
S49 A' 0.049 8.189 eV
S50 A" 0.000 8.198 eV
S51 A" 0.001 8.279 eV
S52 A" 0.001 8.320 eV
S53 A" 0.001 8.341 eV
S54 A' 0.007 8.341 eV
S55 A" 0.000 8.345 eV
S56 A" 0.005 8.371 eV
S57 A" 0.001 8.422 eV
S58 A' 0.040 8.425 eV
S59 A" 0.001 8.479 eV
S60 A' 0.020 8.485 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -23624.17

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:27:52

Legacy ID None

System


Full Name 1-Fluoropentacyclo[10.7.1.02,7.08,20.013,18]icosa-1(19),2(7),3,5,8(20),9,11,13,15,17-decaene

Short Name CID10539971

Formula C20H11F

Mass 270.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1459 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM