3,13-Diazahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-1(16),2(10),4,6,8,11(15),17,19,21-nonaen-12-one (C21H14N2O) - excitons of #1470

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.034 4.209 eV
S2 A' 0.561 4.321 eV
S3 A' 0.265 4.976 eV
S4 A" 0.000 5.059 eV
S5 A' 0.283 5.172 eV
S6 A' 0.637 5.341 eV
S7 A' 0.149 5.624 eV
S8 A' 0.073 5.762 eV
S9 A" 0.000 5.931 eV
S10 A' 0.091 5.958 eV
S11 A' 0.013 6.014 eV
S12 A' 0.225 6.081 eV
S13 A' 0.046 6.118 eV
S14 A' 0.144 6.221 eV
S15 A" 0.000 6.315 eV
S16 A" 0.000 6.403 eV
S17 A' 0.125 6.482 eV
S18 A' 0.193 6.589 eV
S19 A' 0.389 6.603 eV
S20 A' 0.438 6.681 eV
S21 A' 0.189 6.713 eV
S22 A" 0.001 6.764 eV
S23 A' 0.020 6.897 eV
S24 A' 0.230 6.923 eV
S25 A" 0.000 6.963 eV
S26 A' 0.003 7.061 eV
S27 A" 0.000 7.117 eV
S28 A" 0.003 7.161 eV
S29 A' 0.054 7.232 eV
S30 A" 0.000 7.266 eV
S31 A" 0.001 7.356 eV
S32 A' 0.117 7.360 eV
S33 A" 0.000 7.379 eV
S34 A' 0.093 7.426 eV
S35 A" 0.001 7.439 eV
S36 A" 0.001 7.496 eV
S37 A' 0.267 7.522 eV
S38 A" 0.002 7.545 eV
S39 A" 0.001 7.554 eV
S40 A' 0.021 7.605 eV
S41 A" 0.003 7.612 eV
S42 A' 0.078 7.657 eV
S43 A" 0.001 7.673 eV
S44 A" 0.000 7.712 eV
S45 A" 0.000 7.744 eV
S46 A" 0.001 7.792 eV
S47 A' 0.044 7.794 eV
S48 A" 0.001 7.812 eV
S49 A" 0.000 7.818 eV
S50 A' 0.173 7.828 eV
S51 A" 0.005 7.852 eV
S52 A' 0.052 7.886 eV
S53 A" 0.001 7.903 eV
S54 A' 0.015 7.926 eV
S55 A" 0.001 7.955 eV
S56 A" 0.002 7.988 eV
S57 A' 0.050 8.024 eV
S58 A" 0.006 8.058 eV
S59 A" 0.002 8.095 eV
S60 A" 0.008 8.100 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -27020.81

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:31:08

Legacy ID None

System


Full Name 3,13-Diazahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-1(16),2(10),4,6,8,11(15),17,19,21-nonaen-12-one

Short Name CID11809063

Formula C21H14N2O

Mass 310.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1470 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM