6,7-Difluoro-3,11-dithiapentacyclo[10.8.0.02,10.04,9.014,19]icosa-1(20),2(10),4,6,8,12,14,16,18-nonaene (C18H8F2S2) - excitons of #1472

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.199 3.908 eV
S2 A' 0.123 4.221 eV
S3 A' 0.265 4.609 eV
S4 A" 0.000 4.814 eV
S5 A' 0.432 4.817 eV
S6 A' 0.771 5.175 eV
S7 A' 0.148 5.331 eV
S8 A" 0.000 5.419 eV
S9 A' 0.038 5.611 eV
S10 A" 0.000 5.709 eV
S11 A' 0.094 5.769 eV
S12 A' 0.143 5.788 eV
S13 A' 0.091 6.059 eV
S14 A' 1.179 6.065 eV
S15 A' 0.136 6.213 eV
S16 A" 0.000 6.214 eV
S17 A' 0.036 6.402 eV
S18 A' 0.007 6.556 eV
S19 A' 0.363 6.573 eV
S20 A" 0.000 6.590 eV
S21 A' 0.148 6.735 eV
S22 A" 0.001 6.774 eV
S23 A' 0.024 6.813 eV
S24 A" 0.000 6.919 eV
S25 A' 0.003 6.938 eV
S26 A" 0.000 6.955 eV
S27 A" 0.005 7.067 eV
S28 A" 0.002 7.103 eV
S29 A' 0.027 7.112 eV
S30 A' 0.114 7.184 eV
S31 A" 0.007 7.204 eV
S32 A' 0.290 7.236 eV
S33 A" 0.001 7.279 eV
S34 A" 0.001 7.307 eV
S35 A" 0.000 7.328 eV
S36 A' 0.018 7.360 eV
S37 A" 0.001 7.392 eV
S38 A' 0.245 7.419 eV
S39 A" 0.000 7.464 eV
S40 A' 0.029 7.533 eV
S41 A" 0.002 7.581 eV
S42 A' 0.014 7.598 eV
S43 A" 0.003 7.644 eV
S44 A' 0.017 7.673 eV
S45 A" 0.000 7.700 eV
S46 A" 0.000 7.731 eV
S47 A' 0.112 7.794 eV
S48 A" 0.001 7.808 eV
S49 A" 0.001 7.850 eV
S50 A" 0.000 7.866 eV
S51 A' 0.057 7.895 eV
S52 A" 0.001 7.926 eV
S53 A' 0.328 7.944 eV
S54 A" 0.000 7.955 eV
S55 A" 0.000 7.988 eV
S56 A" 0.007 8.038 eV
S57 A" 0.002 8.071 eV
S58 A" 0.000 8.161 eV
S59 A' 0.004 8.194 eV
S60 A" 0.003 8.226 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -45891.06

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:31:36

Legacy ID None

System


Full Name 6,7-Difluoro-3,11-dithiapentacyclo[10.8.0.02,10.04,9.014,19]icosa-1(20),2(10),4,6,8,12,14,16,18-nonaene

Short Name CID118333926

Formula C18H8F2S2

Mass 326.4 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1472 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM