16-Thiahexacyclo[12.11.0.02,7.08,13.015,23.017,22]pentacosa-1(14),2,4,6,8,10,12,15(23),17,19,21,24-dodecaene (C24H14S) - excitons of #1479

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.034 4.133 eV
S2 A' 0.151 4.364 eV
S3 A' 0.030 4.602 eV
S4 A' 0.224 4.866 eV
S5 A' 0.782 4.923 eV
S6 A' 0.503 4.981 eV
S7 A' 0.062 5.216 eV
S8 A' 0.680 5.362 eV
S9 A' 0.148 5.442 eV
S10 A' 0.386 5.561 eV
S11 A" 0.000 5.638 eV
S12 A' 0.024 5.695 eV
S13 A' 0.066 5.772 eV
S14 A' 0.208 5.891 eV
S15 A' 0.114 6.020 eV
S16 A' 0.046 6.142 eV
S17 A' 0.010 6.215 eV
S18 A' 0.246 6.273 eV
S19 A' 0.142 6.359 eV
S20 A' 0.090 6.447 eV
S21 A" 0.000 6.455 eV
S22 A' 0.043 6.531 eV
S23 A' 0.009 6.600 eV
S24 A' 0.048 6.627 eV
S25 A' 0.103 6.749 eV
S26 A' 0.418 6.837 eV
S27 A' 0.134 6.898 eV
S28 A" 0.000 6.947 eV
S29 A' 0.134 6.976 eV
S30 A' 0.036 7.060 eV
S31 A" 0.001 7.102 eV
S32 A' 0.078 7.144 eV
S33 A" 0.002 7.160 eV
S34 A' 0.005 7.186 eV
S35 A" 0.000 7.199 eV
S36 A' 0.365 7.208 eV
S37 A" 0.000 7.235 eV
S38 A' 0.077 7.294 eV
S39 A" 0.001 7.305 eV
S40 A" 0.003 7.348 eV
S41 A' 0.034 7.348 eV
S42 A" 0.001 7.349 eV
S43 A' 0.029 7.389 eV
S44 A" 0.000 7.391 eV
S45 A' 0.201 7.401 eV
S46 A" 0.000 7.430 eV
S47 A" 0.002 7.439 eV
S48 A' 0.103 7.479 eV
S49 A" 0.000 7.488 eV
S50 A' 0.364 7.549 eV
S51 A" 0.000 7.585 eV
S52 A" 0.000 7.603 eV
S53 A" 0.000 7.640 eV
S54 A" 0.001 7.679 eV
S55 A' 0.239 7.682 eV
S56 A' 0.132 7.697 eV
S57 A' 0.068 7.717 eV
S58 A" 0.011 7.732 eV
S59 A" 0.000 7.737 eV
S60 A" 0.001 7.777 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -35939.74

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:33:08

Legacy ID None

System


Full Name 16-Thiahexacyclo[12.11.0.02,7.08,13.015,23.017,22]pentacosa-1(14),2,4,6,8,10,12,15(23),17,19,21,24-dodecaene

Short Name CID13409688

Formula C24H14S

Mass 334.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1479 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM