5,7-Dimethyl-6-thiapentacyclo[9.7.1.02,10.04,8.015,19]nonadeca-1(18),2,4,7,9,11,13,15(19),16-nonaene (C20H14S) - excitons of #1483

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B1 0.061 3.637 eV
S2 A1 0.301 3.691 eV
S3 B1 0.004 4.282 eV
S4 B1 0.002 4.527 eV
S5 A1 1.146 4.654 eV
S6 B1 0.010 4.936 eV
S7 A1 0.436 5.084 eV
S8 B2 0.000 5.194 eV
S9 A1 0.013 5.515 eV
S10 B1 0.406 5.546 eV
S11 B1 0.010 5.828 eV
S12 A1 0.054 5.983 eV
S13 A2 0.000 6.004 eV
S14 A2 0.000 6.264 eV
S15 B2 0.007 6.295 eV
S16 A1 0.251 6.299 eV
S17 A1 0.942 6.371 eV
S18 B1 0.036 6.388 eV
S19 B1 0.480 6.556 eV
S20 B1 0.182 6.618 eV
S21 A1 0.063 6.651 eV
S22 B2 0.002 6.653 eV
S23 A2 0.000 6.669 eV
S24 A2 0.000 6.707 eV
S25 B2 0.000 6.764 eV
S26 B1 0.079 6.764 eV
S27 A1 0.002 6.918 eV
S28 A1 0.051 6.989 eV
S29 B2 0.001 7.041 eV
S30 A2 0.000 7.114 eV
S31 B2 0.002 7.199 eV
S32 A2 0.000 7.302 eV
S33 B1 0.005 7.321 eV
S34 B2 0.000 7.354 eV
S35 A2 0.000 7.395 eV
S36 A1 0.004 7.466 eV
S37 A2 0.000 7.490 eV
S38 B2 0.006 7.546 eV
S39 B2 0.001 7.636 eV
S40 B2 0.000 7.643 eV
S41 A2 0.000 7.655 eV
S42 B1 0.671 7.686 eV
S43 A2 0.000 7.689 eV
S44 A2 0.000 7.778 eV
S45 A2 0.000 7.781 eV
S46 A1 0.087 7.815 eV
S47 B2 0.001 7.906 eV
S48 A2 0.000 7.908 eV
S49 B1 0.014 7.934 eV
S50 A1 0.000 7.938 eV
S51 B2 0.002 7.981 eV
S52 A2 0.000 8.012 eV
S53 A1 0.053 8.070 eV
S54 B1 0.001 8.081 eV
S55 A2 0.000 8.085 eV
S56 B2 0.003 8.097 eV
S57 B2 0.000 8.125 eV
S58 A1 0.311 8.133 eV
S59 B2 0.004 8.166 eV
S60 A2 0.000 8.169 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -31791.63

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:34:18

Legacy ID None

System


Full Name 5,7-Dimethyl-6-thiapentacyclo[9.7.1.02,10.04,8.015,19]nonadeca-1(18),2,4,7,9,11,13,15(19),16-nonaene

Short Name CID13568975

Formula C20H14S

Mass 286.4 u

Point Group C2v

Orientation zx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1483 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM