4-Methylhexacyclo[14.7.1.02,7.08,24.09,14.017,22]tetracosa-1(23),2(7),3,5,8(24),9,11,13,15,17,19,21-dodecaene (C25H16) - excitons of #1491

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.146 3.388 eV
S2 0.009 3.827 eV
S3 0.223 3.860 eV
S4 0.245 4.418 eV
S5 0.148 4.785 eV
S6 0.361 4.911 eV
S7 0.119 5.071 eV
S8 0.637 5.249 eV
S9 0.540 5.333 eV
S10 0.362 5.465 eV
S11 0.141 5.540 eV
S12 0.460 5.685 eV
S13 0.281 5.902 eV
S14 0.255 5.972 eV
S15 0.171 6.090 eV
S16 0.391 6.118 eV
S17 0.110 6.219 eV
S18 0.000 6.230 eV
S19 0.146 6.340 eV
S20 0.000 6.376 eV
S21 0.019 6.450 eV
S22 0.184 6.521 eV
S23 0.036 6.605 eV
S24 0.569 6.686 eV
S25 0.222 6.724 eV
S26 0.202 6.742 eV
S27 0.003 6.781 eV
S28 0.007 6.894 eV
S29 0.007 6.911 eV
S30 0.095 6.924 eV
S31 0.000 6.957 eV
S32 0.052 7.015 eV
S33 0.000 7.034 eV
S34 0.001 7.168 eV
S35 0.216 7.212 eV
S36 0.055 7.264 eV
S37 0.002 7.302 eV
S38 0.002 7.305 eV
S39 0.000 7.370 eV
S40 0.001 7.377 eV
S41 0.182 7.404 eV
S42 0.035 7.433 eV
S43 0.004 7.460 eV
S44 0.000 7.465 eV
S45 0.023 7.500 eV
S46 0.011 7.540 eV
S47 0.118 7.563 eV
S48 0.007 7.581 eV
S49 0.002 7.598 eV
S50 0.008 7.658 eV
S51 0.002 7.675 eV
S52 0.060 7.691 eV
S53 0.034 7.737 eV
S54 0.020 7.749 eV
S55 0.001 7.771 eV
S56 0.004 7.781 eV
S57 0.002 7.791 eV
S58 0.116 7.808 eV
S59 0.003 7.875 eV
S60 0.003 7.888 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -26172.92

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:36:37

Legacy ID None

System


Full Name 4-Methylhexacyclo[14.7.1.02,7.08,24.09,14.017,22]tetracosa-1(23),2(7),3,5,8(24),9,11,13,15,17,19,21-dodecaene

Short Name CID146254

Formula C25H16

Mass 316.4 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1491 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM