2-Nitropentacyclo[12.3.1.04,17.07,16.010,15]octadeca-1(18),2,4(17),5,7(16),8,10(15),11,13-nonaene (C18H9NO2) - excitons of #1497

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.149 3.042 eV
S2 A' 0.284 3.776 eV
S3 A' 0.082 3.807 eV
S4 A" 0.000 3.952 eV
S5 A" 0.000 4.445 eV
S6 A' 0.137 4.653 eV
S7 A' 0.313 4.901 eV
S8 A' 0.060 5.017 eV
S9 A' 0.098 5.074 eV
S10 A' 0.032 5.168 eV
S11 A' 0.062 5.369 eV
S12 A' 0.204 5.708 eV
S13 A" 0.000 5.750 eV
S14 A' 0.016 5.877 eV
S15 A" 0.000 5.921 eV
S16 A' 0.037 5.941 eV
S17 A' 0.132 5.966 eV
S18 A" 0.000 6.096 eV
S19 A' 0.127 6.151 eV
S20 A' 0.520 6.191 eV
S21 A' 0.053 6.348 eV
S22 A" 0.000 6.460 eV
S23 A' 0.259 6.503 eV
S24 A' 0.140 6.575 eV
S25 A' 0.002 6.672 eV
S26 A" 0.000 6.881 eV
S27 A' 1.113 6.892 eV
S28 A' 0.040 7.129 eV
S29 A' 0.615 7.193 eV
S30 A" 0.000 7.194 eV
S31 A" 0.000 7.222 eV
S32 A" 0.000 7.366 eV
S33 A' 0.128 7.374 eV
S34 A" 0.001 7.497 eV
S35 A' 0.510 7.503 eV
S36 A" 0.001 7.525 eV
S37 A' 0.407 7.620 eV
S38 A' 0.058 7.639 eV
S39 A" 0.000 7.719 eV
S40 A' 0.144 7.729 eV
S41 A" 0.000 7.738 eV
S42 A" 0.000 7.748 eV
S43 A" 0.000 7.823 eV
S44 A" 0.000 7.868 eV
S45 A' 0.063 7.869 eV
S46 A' 0.576 7.933 eV
S47 A" 0.003 7.957 eV
S48 A" 0.001 7.961 eV
S49 A' 0.086 7.974 eV
S50 A" 0.000 8.001 eV
S51 A" 0.002 8.067 eV
S52 A' 0.064 8.072 eV
S53 A" 0.005 8.149 eV
S54 A' 0.001 8.190 eV
S55 A" 0.000 8.196 eV
S56 A" 0.000 8.209 eV
S57 A" 0.002 8.248 eV
S58 A' 0.015 8.253 eV
S59 A" 0.001 8.300 eV
S60 A" 0.000 8.314 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -24382.17

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:38:08

Legacy ID None

System


Full Name 2-Nitropentacyclo[12.3.1.04,17.07,16.010,15]octadeca-1(18),2,4(17),5,7(16),8,10(15),11,13-nonaene

Short Name CID149183

Formula C18H9NO2

Mass 271.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1497 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM