15-Nitrohexacyclo[12.8.0.02,11.03,8.04,21.017,22]docosa-1(14),2(11),3(8),4,6,9,12,15,17(22),18,20-undecaene (C22H11NO2) - excitons of #1498

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A" 0.000 3.698 eV
S2 A' 0.039 3.783 eV
S3 A' 0.255 3.845 eV
S4 A" 0.000 4.406 eV
S5 A' 0.011 4.482 eV
S6 A' 0.002 4.629 eV
S7 A' 0.032 4.734 eV
S8 A' 0.637 4.993 eV
S9 A" 0.000 5.068 eV
S10 A' 0.435 5.073 eV
S11 A' 0.121 5.141 eV
S12 A' 0.145 5.323 eV
S13 A' 0.095 5.366 eV
S14 A' 0.060 5.510 eV
S15 A' 0.061 5.733 eV
S16 A' 0.107 5.778 eV
S17 A" 0.000 5.820 eV
S18 A' 0.049 5.999 eV
S19 A" 0.000 6.142 eV
S20 A' 0.003 6.189 eV
S21 A" 0.000 6.286 eV
S22 A' 0.067 6.302 eV
S23 A' 0.067 6.314 eV
S24 A' 0.290 6.421 eV
S25 A" 0.004 6.455 eV
S26 A" 0.000 6.631 eV
S27 A' 0.497 6.637 eV
S28 A' 0.103 6.680 eV
S29 A' 0.138 6.722 eV
S30 A' 0.008 6.827 eV
S31 A" 0.011 6.899 eV
S32 A' 1.292 6.960 eV
S33 A" 0.000 7.007 eV
S34 A' 0.103 7.080 eV
S35 A" 0.000 7.129 eV
S36 A' 0.227 7.158 eV
S37 A" 0.000 7.182 eV
S38 A' 0.127 7.208 eV
S39 A" 0.000 7.229 eV
S40 A' 0.293 7.229 eV
S41 A' 0.044 7.266 eV
S42 A' 0.235 7.366 eV
S43 A" 0.000 7.413 eV
S44 A' 0.039 7.437 eV
S45 A' 0.708 7.458 eV
S46 A" 0.002 7.486 eV
S47 A" 0.000 7.497 eV
S48 A' 1.226 7.500 eV
S49 A" 0.009 7.509 eV
S50 A" 0.020 7.564 eV
S51 A" 0.000 7.624 eV
S52 A" 0.004 7.668 eV
S53 A' 0.045 7.681 eV
S54 A" 0.003 7.701 eV
S55 A" 0.009 7.741 eV
S56 A' 0.000 7.761 eV
S57 A' 0.092 7.774 eV
S58 A" 0.003 7.815 eV
S59 A' 0.134 7.818 eV
S60 A" 0.002 7.852 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -28563.23

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:38:22

Legacy ID None

System


Full Name 15-Nitrohexacyclo[12.8.0.02,11.03,8.04,21.017,22]docosa-1(14),2(11),3(8),4,6,9,12,15,17(22),18,20-undecaene

Short Name CID149916

Formula C22H11NO2

Mass 321.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1498 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM