6,7-Diazahexacyclo[12.12.0.02,11.04,9.016,25.018,23]hexacosa-1(26),2,4,6,8,10,12,14,16,18,20,22,24-tridecaene (C24H14N2) - excitons of #1513

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.065 3.301 eV
S2 A' 0.041 3.512 eV
S3 A" 0.000 3.870 eV
S4 A' 1.228 4.197 eV
S5 A' 0.018 4.332 eV
S6 A" 0.005 4.373 eV
S7 A' 0.735 4.382 eV
S8 A' 0.369 4.706 eV
S9 A' 0.067 4.810 eV
S10 A' 0.911 5.152 eV
S11 A' 0.025 5.409 eV
S12 A' 0.955 5.463 eV
S13 A" 0.004 5.513 eV
S14 A' 0.572 5.560 eV
S15 A' 0.002 5.582 eV
S16 A' 0.018 5.733 eV
S17 A' 0.003 5.842 eV
S18 A" 0.000 5.869 eV
S19 A' 0.175 5.927 eV
S20 A" 0.000 6.010 eV
S21 A" 0.000 6.145 eV
S22 A' 0.488 6.156 eV
S23 A' 0.006 6.277 eV
S24 A" 0.000 6.329 eV
S25 A' 0.047 6.338 eV
S26 A' 0.014 6.450 eV
S27 A" 0.000 6.464 eV
S28 A' 0.037 6.525 eV
S29 A' 0.218 6.552 eV
S30 A" 0.000 6.616 eV
S31 A' 0.252 6.623 eV
S32 A' 0.014 6.674 eV
S33 A' 0.025 6.718 eV
S34 A" 0.000 6.737 eV
S35 A' 0.316 6.754 eV
S36 A" 0.000 6.822 eV
S37 A" 0.000 6.887 eV
S38 A' 0.013 6.892 eV
S39 A" 0.001 6.908 eV
S40 A' 0.006 7.020 eV
S41 A" 0.000 7.026 eV
S42 A' 0.022 7.041 eV
S43 A' 0.018 7.084 eV
S44 A' 0.043 7.139 eV
S45 A" 0.001 7.262 eV
S46 A" 0.000 7.302 eV
S47 A' 0.037 7.306 eV
S48 A" 0.000 7.321 eV
S49 A" 0.000 7.347 eV
S50 A' 0.001 7.398 eV
S51 A' 0.066 7.438 eV
S52 A" 0.002 7.498 eV
S53 A" 0.000 7.510 eV
S54 A" 0.000 7.553 eV
S55 A' 0.006 7.565 eV
S56 A" 0.000 7.573 eV
S57 A' 0.033 7.580 eV
S58 A' 0.110 7.642 eV
S59 A" 0.001 7.662 eV
S60 A" 0.000 7.687 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -28082.06

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:42:55

Legacy ID None

System


Full Name 6,7-Diazahexacyclo[12.12.0.02,11.04,9.016,25.018,23]hexacosa-1(26),2,4,6,8,10,12,14,16,18,20,22,24-tridecaene

Short Name CID23293717

Formula C24H14N2

Mass 330.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1513 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM