7-Methylhexacyclo[12.8.0.02,11.03,8.04,21.017,22]docosa-1(14),2(11),3(8),4,6,9,12,15,17(22),18,20-undecaene (C23H14) - excitons of #1524

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.249 3.755 eV
S2 A' 0.059 3.777 eV
S3 A' 0.006 4.461 eV
S4 A' 0.008 4.720 eV
S5 A' 0.791 4.987 eV
S6 A' 0.372 5.074 eV
S7 A' 0.029 5.146 eV
S8 A' 0.267 5.264 eV
S9 A' 0.005 5.318 eV
S10 A' 0.004 5.443 eV
S11 A' 0.149 5.696 eV
S12 A' 0.120 5.748 eV
S13 A' 0.000 5.985 eV
S14 A' 0.001 6.196 eV
S15 A' 0.005 6.284 eV
S16 A' 0.336 6.389 eV
S17 A' 0.100 6.397 eV
S18 A" 0.000 6.507 eV
S19 A" 0.000 6.554 eV
S20 A' 0.618 6.568 eV
S21 A' 0.006 6.659 eV
S22 A' 0.043 6.666 eV
S23 A" 0.001 6.716 eV
S24 A" 0.002 6.822 eV
S25 A' 1.338 6.929 eV
S26 A" 0.000 6.979 eV
S27 A' 0.236 6.997 eV
S28 A' 0.122 7.090 eV
S29 A' 0.020 7.171 eV
S30 A" 0.000 7.177 eV
S31 A" 0.002 7.199 eV
S32 A' 0.086 7.236 eV
S33 A" 0.001 7.249 eV
S34 A' 0.074 7.284 eV
S35 A" 0.000 7.301 eV
S36 A' 0.576 7.315 eV
S37 A" 0.001 7.416 eV
S38 A" 0.000 7.459 eV
S39 A' 1.871 7.471 eV
S40 A' 0.193 7.490 eV
S41 A" 0.002 7.549 eV
S42 A" 0.000 7.558 eV
S43 A" 0.001 7.577 eV
S44 A" 0.006 7.629 eV
S45 A' 0.056 7.642 eV
S46 A" 0.001 7.665 eV
S47 A" 0.000 7.696 eV
S48 A" 0.000 7.720 eV
S49 A' 0.194 7.732 eV
S50 A' 0.050 7.789 eV
S51 A" 0.000 7.802 eV
S52 A" 0.001 7.830 eV
S53 A" 0.000 7.856 eV
S54 A' 0.006 7.878 eV
S55 A" 0.000 7.951 eV
S56 A' 0.017 7.956 eV
S57 A' 0.007 8.005 eV
S58 A' 0.041 8.084 eV
S59 A" 0.000 8.115 eV
S60 A" 0.000 8.117 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -24067.49

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:45:47

Legacy ID None

System


Full Name 7-Methylhexacyclo[12.8.0.02,11.03,8.04,21.017,22]docosa-1(14),2(11),3(8),4,6,9,12,15,17(22),18,20-undecaene

Short Name CID38944

Formula C23H14

Mass 290.4 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1524 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM