Pentacyclo[11.8.0.03,11.05,9.015,20]henicosa-1(21),2,4,6,9,11,13,15,17,19-decaene (C21H14) - excitons of #1544

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.123 3.058 eV
S2 A' 0.005 3.682 eV
S3 A' 0.164 4.381 eV
S4 A' 0.032 4.531 eV
S5 A' 2.499 4.956 eV
S6 A' 1.511 5.040 eV
S7 A' 0.001 5.379 eV
S8 A' 0.180 5.532 eV
S9 A' 0.055 5.575 eV
S10 A' 0.077 5.706 eV
S11 A' 0.195 5.852 eV
S12 A' 0.176 6.082 eV
S13 A" 0.000 6.191 eV
S14 A" 0.000 6.219 eV
S15 A' 0.020 6.281 eV
S16 A' 0.023 6.464 eV
S17 A' 0.015 6.495 eV
S18 A" 0.000 6.503 eV
S19 A" 0.000 6.544 eV
S20 A" 0.000 6.557 eV
S21 A" 0.000 6.588 eV
S22 A' 0.075 6.607 eV
S23 A" 0.000 6.696 eV
S24 A' 0.024 6.783 eV
S25 A" 0.000 6.823 eV
S26 A' 0.003 6.876 eV
S27 A' 0.278 6.975 eV
S28 A" 0.000 7.100 eV
S29 A' 0.000 7.124 eV
S30 A" 0.000 7.150 eV
S31 A' 0.003 7.228 eV
S32 A" 0.000 7.292 eV
S33 A' 0.065 7.389 eV
S34 A' 0.003 7.414 eV
S35 A" 0.000 7.464 eV
S36 A' 0.012 7.476 eV
S37 A' 0.027 7.522 eV
S38 A" 0.000 7.552 eV
S39 A" 0.001 7.599 eV
S40 A' 0.119 7.638 eV
S41 A" 0.000 7.646 eV
S42 A" 0.000 7.680 eV
S43 A" 0.001 7.706 eV
S44 A' 0.048 7.785 eV
S45 A" 0.001 7.851 eV
S46 A' 0.020 7.858 eV
S47 A" 0.000 7.862 eV
S48 A" 0.007 7.956 eV
S49 A" 0.001 7.973 eV
S50 A' 0.006 7.985 eV
S51 A" 0.000 8.096 eV
S52 A" 0.010 8.105 eV
S53 A" 0.003 8.139 eV
S54 A" 0.000 8.154 eV
S55 A' 0.014 8.155 eV
S56 A" 0.002 8.176 eV
S57 A' 0.073 8.198 eV
S58 A" 0.002 8.213 eV
S59 A" 0.002 8.231 eV
S60 A' 0.017 8.243 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -21991.87

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:51:07

Legacy ID None

System


Full Name Pentacyclo[11.8.0.03,11.05,9.015,20]henicosa-1(21),2,4,6,9,11,13,15,17,19-decaene

Short Name CID59787207

Formula C21H14

Mass 266.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1544 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM