9,14-Dithiahexacyclo[11.7.0.02,10.03,8.04,19.015,20]icosa-1(13),2(10),3,5,7,11,15,17,19-nonaene (C18H8S2) - excitons of #1545

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A1 0.004 4.070 eV
S2 B1 0.108 4.211 eV
S3 B1 0.109 4.797 eV
S4 A1 0.349 4.947 eV
S5 B1 0.227 5.051 eV
S6 A2 0.000 5.193 eV
S7 B2 0.000 5.305 eV
S8 A1 0.189 5.404 eV
S9 B1 0.067 5.459 eV
S10 A1 0.008 5.576 eV
S11 B1 0.302 5.759 eV
S12 A1 0.132 5.855 eV
S13 B1 0.357 5.964 eV
S14 A1 0.111 6.018 eV
S15 B1 0.428 6.165 eV
S16 B2 0.000 6.200 eV
S17 A1 0.542 6.288 eV
S18 A2 0.000 6.324 eV
S19 B1 0.244 6.346 eV
S20 A1 0.001 6.505 eV
S21 B1 0.024 6.654 eV
S22 A1 0.128 6.768 eV
S23 B1 0.093 6.795 eV
S24 B2 0.001 6.911 eV
S25 A1 0.104 7.028 eV
S26 A2 0.000 7.029 eV
S27 A2 0.000 7.129 eV
S28 B2 0.000 7.196 eV
S29 A1 0.003 7.199 eV
S30 B1 0.173 7.230 eV
S31 A2 0.000 7.238 eV
S32 A2 0.000 7.307 eV
S33 B1 0.083 7.343 eV
S34 B2 0.000 7.353 eV
S35 B2 0.002 7.403 eV
S36 A2 0.000 7.412 eV
S37 B1 0.000 7.484 eV
S38 B2 0.004 7.519 eV
S39 A1 0.030 7.527 eV
S40 A2 0.000 7.565 eV
S41 B2 0.001 7.582 eV
S42 A2 0.000 7.593 eV
S43 A1 0.000 7.600 eV
S44 B2 0.001 7.625 eV
S45 A2 0.000 7.651 eV
S46 A2 0.000 7.659 eV
S47 B1 0.278 7.715 eV
S48 B2 0.010 7.716 eV
S49 A1 0.371 7.762 eV
S50 B2 0.000 7.777 eV
S51 A2 0.000 7.794 eV
S52 B2 0.000 7.844 eV
S53 A2 0.000 7.858 eV
S54 B2 0.001 7.886 eV
S55 A2 0.000 7.896 eV
S56 B1 0.366 7.902 eV
S57 B2 0.003 7.970 eV
S58 A1 0.587 7.998 eV
S59 A2 0.000 8.039 eV
S60 A1 0.019 8.058 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -40456.84

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:51:21

Legacy ID None

System


Full Name 9,14-Dithiahexacyclo[11.7.0.02,10.03,8.04,19.015,20]icosa-1(13),2(10),3,5,7,11,15,17,19-nonaene

Short Name CID6428181

Formula C18H8S2

Mass 288.4 u

Point Group C2v

Orientation xz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1545 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM