2-Azaheptacyclo[14.6.2.04,21.07,20.010,19.013,18.017,22]tetracosa-1,3,5,7(20),8,10(19),11,13(18),14,16,21,23-dodecaene (C23H11N) - excitons of #1563

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.014 3.636 eV
S2 A' 0.000 3.950 eV
S3 A' 0.098 4.725 eV
S4 A" 0.002 4.725 eV
S5 A' 0.065 4.749 eV
S6 A' 0.293 4.832 eV
S7 A' 0.830 4.949 eV
S8 A' 0.769 5.023 eV
S9 A' 0.122 5.109 eV
S10 A" 0.000 5.227 eV
S11 A' 0.067 5.230 eV
S12 A' 0.067 5.244 eV
S13 A' 0.124 5.379 eV
S14 A' 0.005 5.735 eV
S15 A' 0.087 5.815 eV
S16 A' 0.003 5.953 eV
S17 A' 0.005 6.129 eV
S18 A' 0.004 6.156 eV
S19 A' 0.032 6.221 eV
S20 A' 0.015 6.384 eV
S21 A" 0.002 6.425 eV
S22 A' 0.011 6.427 eV
S23 A' 0.014 6.518 eV
S24 A' 0.000 6.695 eV
S25 A" 0.000 6.714 eV
S26 A" 0.000 6.742 eV
S27 A' 0.010 6.750 eV
S28 A" 0.000 6.874 eV
S29 A' 0.017 6.875 eV
S30 A' 0.052 6.930 eV
S31 A" 0.000 6.989 eV
S32 A' 1.078 6.996 eV
S33 A' 0.304 7.104 eV
S34 A" 0.000 7.121 eV
S35 A' 1.447 7.126 eV
S36 A' 0.099 7.173 eV
S37 A" 0.000 7.174 eV
S38 A" 0.000 7.220 eV
S39 A' 0.155 7.306 eV
S40 A" 0.000 7.342 eV
S41 A' 0.521 7.349 eV
S42 A" 0.000 7.430 eV
S43 A" 0.001 7.513 eV
S44 A' 0.981 7.587 eV
S45 A" 0.002 7.589 eV
S46 A" 0.000 7.614 eV
S47 A" 0.001 7.626 eV
S48 A' 0.677 7.664 eV
S49 A" 0.004 7.717 eV
S50 A' 0.012 7.742 eV
S51 A" 0.000 7.744 eV
S52 A' 0.703 7.772 eV
S53 A" 0.000 7.773 eV
S54 A' 0.425 7.807 eV
S55 A" 0.000 7.835 eV
S56 A" 0.002 7.845 eV
S57 A" 0.000 7.910 eV
S58 A' 0.131 7.944 eV
S59 A" 0.000 7.951 eV
S60 A" 0.003 7.969 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -25508.93

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:55:49

Legacy ID None

System


Full Name 2-Azaheptacyclo[14.6.2.04,21.07,20.010,19.013,18.017,22]tetracosa-1,3,5,7(20),8,10(19),11,13(18),14,16,21,23-dodecaene

Short Name azacoronene

Formula C23H11N

Mass 301.3 u

Point Group Cs

Orientation yx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1563 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM