Pentacyclo[10.6.2.02,8.09,19.016,20]icosa-1,3,5,7,9(19),10,12(20),13,15,17-decaene (C20H12) - excitons of #1565

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B1 0.009 1.940 eV
S2 A1 0.249 3.056 eV
S3 B1 0.081 4.177 eV
S4 B1 0.008 4.286 eV
S5 A1 1.482 4.417 eV
S6 A1 0.884 4.694 eV
S7 B1 0.050 4.714 eV
S8 A1 0.295 4.958 eV
S9 B1 0.004 5.010 eV
S10 B1 0.121 5.256 eV
S11 A1 0.151 5.326 eV
S12 A2 0.000 5.825 eV
S13 B1 0.058 5.859 eV
S14 A1 0.058 6.072 eV
S15 B2 0.001 6.141 eV
S16 B2 0.001 6.169 eV
S17 A1 0.202 6.207 eV
S18 B1 0.054 6.221 eV
S19 A2 0.000 6.293 eV
S20 A2 0.000 6.341 eV
S21 B1 0.002 6.417 eV
S22 B2 0.000 6.532 eV
S23 A1 0.004 6.549 eV
S24 A2 0.000 6.676 eV
S25 A1 0.214 6.714 eV
S26 B1 0.058 6.722 eV
S27 A2 0.000 6.738 eV
S28 B2 0.000 6.795 eV
S29 B2 0.000 6.845 eV
S30 A1 0.933 6.877 eV
S31 A2 0.000 6.912 eV
S32 A2 0.000 7.103 eV
S33 A2 0.000 7.113 eV
S34 A1 0.055 7.170 eV
S35 B2 0.000 7.242 eV
S36 B1 0.349 7.294 eV
S37 A2 0.000 7.299 eV
S38 A1 0.002 7.338 eV
S39 B1 1.050 7.362 eV
S40 B2 0.000 7.366 eV
S41 B2 0.000 7.471 eV
S42 A1 0.461 7.530 eV
S43 B1 0.004 7.545 eV
S44 B2 0.003 7.597 eV
S45 A2 0.000 7.661 eV
S46 A2 0.000 7.669 eV
S47 B1 0.002 7.731 eV
S48 B2 0.003 7.744 eV
S49 A1 0.003 7.760 eV
S50 A2 0.000 7.795 eV
S51 B2 0.001 7.937 eV
S52 A2 0.000 7.938 eV
S53 A1 0.260 7.958 eV
S54 A2 0.000 7.997 eV
S55 B2 0.016 8.002 eV
S56 A2 0.000 8.042 eV
S57 B1 0.238 8.104 eV
S58 B2 0.000 8.126 eV
S59 B1 0.067 8.193 eV
S60 A2 0.000 8.195 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -20921.99

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:56:07

Legacy ID None

System


Full Name Pentacyclo[10.6.2.02,8.09,19.016,20]icosa-1,3,5,7,9(19),10,12(20),13,15,17-decaene

Short Name azuleno(1,2,3-cd)phenolene

Formula C20H12

Mass 252.3 u

Point Group C2v

Orientation zx

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1565 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM