Pentacyclo[8.8.0.02,7.03,17.013,18]octadeca-1(10),2(7),3,5,8,11,13(18),14,16-nonaene (C18H10) - excitons of #1583

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B2 0.005 3.687 eV
S2 A1 0.033 4.159 eV
S3 B2 0.100 4.255 eV
S4 A1 0.007 4.797 eV
S5 B2 0.309 4.983 eV
S6 A1 0.115 5.281 eV
S7 A1 0.000 5.552 eV
S8 B2 0.607 5.746 eV
S9 B2 0.290 5.990 eV
S10 A1 0.807 6.294 eV
S11 B1 0.000 6.371 eV
S12 B2 0.557 6.389 eV
S13 A2 0.000 6.506 eV
S14 A1 0.041 6.675 eV
S15 B2 0.172 6.681 eV
S16 A1 0.002 6.787 eV
S17 B2 0.007 6.838 eV
S18 A1 0.353 6.873 eV
S19 A2 0.000 6.907 eV
S20 B2 0.001 6.973 eV
S21 B1 0.001 7.058 eV
S22 A1 0.433 7.218 eV
S23 A1 0.268 7.342 eV
S24 A2 0.000 7.347 eV
S25 B2 0.647 7.368 eV
S26 B1 0.002 7.401 eV
S27 A2 0.000 7.406 eV
S28 B1 0.000 7.459 eV
S29 A2 0.000 7.499 eV
S30 B1 0.015 7.613 eV
S31 A2 0.000 7.666 eV
S32 A1 0.597 7.755 eV
S33 B1 0.000 7.766 eV
S34 B2 0.396 7.776 eV
S35 B1 0.000 7.888 eV
S36 A2 0.000 7.890 eV
S37 A2 0.000 7.973 eV
S38 A1 0.035 7.983 eV
S39 B2 0.057 8.084 eV
S40 B1 0.001 8.152 eV
S41 A1 0.009 8.194 eV
S42 A2 0.000 8.203 eV
S43 B1 0.000 8.205 eV
S44 B1 0.004 8.222 eV
S45 B2 0.003 8.234 eV
S46 A2 0.000 8.234 eV
S47 A2 0.000 8.303 eV
S48 B1 0.001 8.337 eV
S49 A2 0.000 8.360 eV
S50 A2 0.000 8.375 eV
S51 B2 0.075 8.378 eV
S52 B1 0.001 8.415 eV
S53 A2 0.000 8.472 eV
S54 B1 0.000 8.513 eV
S55 B2 0.002 8.545 eV
S56 A1 0.326 8.546 eV
S57 A2 0.000 8.577 eV
S58 A2 0.000 8.640 eV
S59 A1 0.133 8.661 eV
S60 A1 0.002 8.674 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -18816.13

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 20:59:40

Legacy ID None

System


Full Name Pentacyclo[8.8.0.02,7.03,17.013,18]octadeca-1(10),2(7),3,5,8,11,13(18),14,16-nonaene

Short Name benzo(ghi)fluoranthene

Formula C18H10

Mass 226.3 u

Point Group C2v

Orientation yz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1583 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM