Hexacyclo[16.3.1.04,21.07,20.08,13.014,19]docosa-1(22),2,4(21),5,7(20),8,10,12,14,16,18-undecaene (C22H12) - excitons of #1585

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.047 3.358 eV
S2 A' 0.094 3.850 eV
S3 A' 0.264 4.097 eV
S4 A' 0.013 4.672 eV
S5 A' 0.252 4.734 eV
S6 A' 0.031 4.900 eV
S7 A' 0.359 5.043 eV
S8 A' 0.028 5.228 eV
S9 A' 0.126 5.456 eV
S10 A' 0.030 5.603 eV
S11 A' 0.267 5.708 eV
S12 A' 0.343 5.773 eV
S13 A' 0.272 5.808 eV
S14 A" 0.000 6.026 eV
S15 A' 0.428 6.053 eV
S16 A' 0.238 6.214 eV
S17 A' 0.213 6.283 eV
S18 A" 0.000 6.367 eV
S19 A' 0.132 6.504 eV
S20 A' 0.381 6.579 eV
S21 A' 0.056 6.684 eV
S22 A' 0.194 6.734 eV
S23 A' 0.017 6.818 eV
S24 A' 0.588 6.867 eV
S25 A' 0.024 6.948 eV
S26 A" 0.000 6.953 eV
S27 A' 0.352 7.163 eV
S28 A" 0.000 7.174 eV
S29 A" 0.002 7.181 eV
S30 A' 0.059 7.187 eV
S31 A" 0.000 7.203 eV
S32 A" 0.000 7.248 eV
S33 A' 1.390 7.282 eV
S34 A" 0.000 7.431 eV
S35 A' 0.088 7.436 eV
S36 A' 0.048 7.468 eV
S37 A" 0.001 7.484 eV
S38 A' 0.018 7.495 eV
S39 A" 0.002 7.497 eV
S40 A" 0.000 7.501 eV
S41 A" 0.001 7.555 eV
S42 A' 0.017 7.603 eV
S43 A" 0.000 7.653 eV
S44 A" 0.011 7.674 eV
S45 A" 0.000 7.688 eV
S46 A" 0.000 7.746 eV
S47 A" 0.001 7.812 eV
S48 A' 0.036 7.815 eV
S49 A' 0.163 7.825 eV
S50 A" 0.000 7.868 eV
S51 A" 0.000 7.890 eV
S52 A" 0.000 7.944 eV
S53 A" 0.003 7.970 eV
S54 A' 0.090 7.974 eV
S55 A' 0.099 8.008 eV
S56 A" 0.001 8.054 eV
S57 A" 0.000 8.069 eV
S58 A' 0.096 8.113 eV
S59 A" 0.001 8.138 eV
S60 A' 0.102 8.138 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -22996.83

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:00:11

Legacy ID None

System


Full Name Hexacyclo[16.3.1.04,21.07,20.08,13.014,19]docosa-1(22),2,4(21),5,7(20),8,10,12,14,16,18-undecaene

Short Name benzo(l)cyclopenta(cd)pyrene

Formula C22H12

Mass 276.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1585 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM