Hexacyclo[11.9.1.114,18.02,7.09,23.022,24]tetracosa-1(23),2,4,6,8,10,12,14,16,18(24),19,21-dodecaene (C24H14) - excitons of #1586

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.507 2.943 eV
S2 0.002 3.823 eV
S3 0.029 4.098 eV
S4 0.011 4.174 eV
S5 0.007 4.268 eV
S6 0.008 4.448 eV
S7 0.032 4.657 eV
S8 0.169 4.948 eV
S9 0.460 5.266 eV
S10 0.373 5.373 eV
S11 0.226 5.448 eV
S12 0.001 5.580 eV
S13 0.004 5.893 eV
S14 0.134 5.945 eV
S15 0.011 5.991 eV
S16 0.026 6.076 eV
S17 0.011 6.125 eV
S18 0.095 6.229 eV
S19 0.238 6.264 eV
S20 0.022 6.323 eV
S21 0.000 6.361 eV
S22 0.513 6.445 eV
S23 0.286 6.494 eV
S24 0.051 6.516 eV
S25 0.077 6.547 eV
S26 0.009 6.576 eV
S27 0.344 6.612 eV
S28 0.057 6.645 eV
S29 0.891 6.687 eV
S30 0.114 6.762 eV
S31 0.215 6.842 eV
S32 0.269 6.853 eV
S33 0.177 6.890 eV
S34 0.092 6.905 eV
S35 0.013 6.930 eV
S36 0.043 6.952 eV
S37 0.053 6.988 eV
S38 0.200 7.009 eV
S39 0.227 7.077 eV
S40 0.077 7.109 eV
S41 0.013 7.184 eV
S42 0.175 7.245 eV
S43 0.195 7.284 eV
S44 0.313 7.303 eV
S45 0.066 7.390 eV
S46 0.111 7.426 eV
S47 0.007 7.495 eV
S48 0.109 7.502 eV
S49 0.012 7.577 eV
S50 0.011 7.594 eV
S51 0.014 7.600 eV
S52 0.047 7.667 eV
S53 0.018 7.676 eV
S54 0.167 7.753 eV
S55 0.194 7.804 eV
S56 0.003 7.837 eV
S57 0.019 7.850 eV
S58 0.001 7.884 eV
S59 0.035 7.914 eV
S60 0.055 7.930 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -25103.14

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:00:26

Legacy ID None

System


Full Name Hexacyclo[11.9.1.114,18.02,7.09,23.022,24]tetracosa-1(23),2,4,6,8,10,12,14,16,18(24),19,21-dodecaene

Short Name benzoperylene

Formula C24H14

Mass 302.4 u

Point Group C1

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1586 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM