3,13-Diazahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-1(16),2(10),4,6,8,11(15),17,19,21-nonaen-14-one (C21H14N2O) - excitons of #1596

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.231 4.310 eV
S2 A' 0.346 4.491 eV
S3 A' 0.153 5.008 eV
S4 A' 0.265 5.129 eV
S5 A" 0.000 5.228 eV
S6 A' 0.979 5.333 eV
S7 A' 0.144 5.601 eV
S8 A' 0.131 5.776 eV
S9 A" 0.000 6.025 eV
S10 A' 0.118 6.081 eV
S11 A" 0.000 6.096 eV
S12 A' 0.338 6.149 eV
S13 A' 0.126 6.257 eV
S14 A' 0.076 6.310 eV
S15 A' 0.066 6.378 eV
S16 A" 0.000 6.389 eV
S17 A' 0.337 6.431 eV
S18 A' 0.150 6.548 eV
S19 A' 0.055 6.587 eV
S20 A' 0.084 6.618 eV
S21 A' 0.049 6.746 eV
S22 A" 0.001 6.792 eV
S23 A' 0.056 6.838 eV
S24 A" 0.000 6.904 eV
S25 A' 0.037 6.959 eV
S26 A" 0.000 7.029 eV
S27 A' 0.001 7.114 eV
S28 A' 0.115 7.150 eV
S29 A" 0.001 7.184 eV
S30 A" 0.000 7.189 eV
S31 A" 0.000 7.255 eV
S32 A' 0.045 7.280 eV
S33 A" 0.000 7.300 eV
S34 A" 0.001 7.354 eV
S35 A' 0.227 7.359 eV
S36 A" 0.001 7.452 eV
S37 A' 0.125 7.515 eV
S38 A" 0.005 7.539 eV
S39 A" 0.001 7.609 eV
S40 A' 0.229 7.627 eV
S41 A" 0.000 7.638 eV
S42 A" 0.002 7.725 eV
S43 A" 0.000 7.737 eV
S44 A" 0.004 7.783 eV
S45 A' 0.018 7.810 eV
S46 A" 0.003 7.812 eV
S47 A" 0.004 7.827 eV
S48 A" 0.001 7.854 eV
S49 A' 0.099 7.855 eV
S50 A' 0.088 7.894 eV
S51 A" 0.000 7.900 eV
S52 A" 0.000 7.904 eV
S53 A' 0.214 7.935 eV
S54 A" 0.001 7.939 eV
S55 A' 0.044 7.969 eV
S56 A" 0.003 7.987 eV
S57 A' 0.065 8.008 eV
S58 A" 0.000 8.009 eV
S59 A' 0.191 8.086 eV
S60 A" 0.007 8.160 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -27020.77

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:02:17

Legacy ID None

System


Full Name 3,13-Diazahexacyclo[14.7.0.02,10.04,9.011,15.017,22]tricosa-1(16),2(10),4,6,8,11(15),17,19,21-nonaen-14-one

Short Name CID9796713

Formula C21H14N2O

Mass 310.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1596 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM