Hexacyclo[10.10.2.02,7.08,24.015,23.016,21]tetracosa-1(22),2,4,6,8,10,12(24),13,15(23),16,18,20-dodecaene (C24H14) - excitons of #1602

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.211 3.842 eV
S2 A' 0.085 3.893 eV
S3 A' 0.035 4.439 eV
S4 A' 0.151 4.749 eV
S5 A' 0.457 4.820 eV
S6 A' 0.102 4.889 eV
S7 A' 0.568 5.078 eV
S8 A' 0.288 5.269 eV
S9 A' 0.750 5.344 eV
S10 A' 0.079 5.395 eV
S11 A' 0.019 5.658 eV
S12 A' 0.149 5.670 eV
S13 A' 0.188 5.838 eV
S14 A' 0.087 5.922 eV
S15 A' 0.021 5.990 eV
S16 A' 0.012 6.160 eV
S17 A' 0.015 6.304 eV
S18 A' 0.511 6.408 eV
S19 A' 0.689 6.509 eV
S20 A" 0.000 6.530 eV
S21 A' 0.167 6.538 eV
S22 A' 0.100 6.663 eV
S23 A" 0.000 6.695 eV
S24 A" 0.000 6.769 eV
S25 A' 0.387 6.788 eV
S26 A" 0.001 6.845 eV
S27 A' 0.249 6.864 eV
S28 A' 0.078 6.911 eV
S29 A' 0.058 6.965 eV
S30 A" 0.000 7.017 eV
S31 A' 0.160 7.048 eV
S32 A' 0.049 7.133 eV
S33 A" 0.002 7.171 eV
S34 A' 0.219 7.173 eV
S35 A" 0.000 7.207 eV
S36 A' 0.452 7.263 eV
S37 A" 0.001 7.295 eV
S38 A" 0.000 7.327 eV
S39 A' 0.317 7.350 eV
S40 A" 0.006 7.411 eV
S41 A" 0.003 7.418 eV
S42 A' 0.150 7.478 eV
S43 A' 0.039 7.546 eV
S44 A' 0.003 7.549 eV
S45 A" 0.000 7.552 eV
S46 A" 0.000 7.562 eV
S47 A" 0.000 7.629 eV
S48 A" 0.000 7.672 eV
S49 A" 0.001 7.685 eV
S50 A' 0.060 7.703 eV
S51 A" 0.000 7.708 eV
S52 A' 0.120 7.708 eV
S53 A" 0.000 7.752 eV
S54 A" 0.001 7.784 eV
S55 A' 0.059 7.801 eV
S56 A' 0.090 7.838 eV
S57 A' 0.091 7.869 eV
S58 A" 0.001 7.877 eV
S59 A" 0.001 7.909 eV
S60 A" 0.003 7.963 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -25103.87

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:03:49

Legacy ID None

System


Full Name Hexacyclo[10.10.2.02,7.08,24.015,23.016,21]tetracosa-1(22),2,4,6,8,10,12(24),13,15(23),16,18,20-dodecaene

Short Name DIBENZO(a,e)PYRENE

Formula C24H14

Mass 302.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1602 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM