Tricyclo[7.4.1.04,14]tetradeca-1(14),2,4,6,8,10,12-heptaene (C14H10) - excitons of #1632

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 B2 0.002 1.691 eV
S2 A1 0.000 3.403 eV
S3 B2 0.224 3.697 eV
S4 A1 0.020 4.164 eV
S5 B2 0.230 5.116 eV
S6 A1 0.301 5.239 eV
S7 A2 0.000 5.736 eV
S8 A2 0.000 5.804 eV
S9 B2 1.080 5.822 eV
S10 B2 0.462 6.144 eV
S11 B1 0.000 6.212 eV
S12 A1 0.629 6.359 eV
S13 A2 0.000 6.454 eV
S14 B1 0.001 6.622 eV
S15 A2 0.000 6.743 eV
S16 A1 0.445 6.875 eV
S17 A2 0.000 6.913 eV
S18 B1 0.000 6.970 eV
S19 A1 0.487 6.981 eV
S20 B1 0.001 6.996 eV
S21 A2 0.000 7.129 eV
S22 A1 0.353 7.191 eV
S23 B1 0.005 7.318 eV
S24 B2 0.004 7.365 eV
S25 B1 0.001 7.399 eV
S26 A2 0.000 7.424 eV
S27 A1 0.004 7.472 eV
S28 A2 0.000 7.685 eV
S29 B1 0.013 7.700 eV
S30 A2 0.000 7.716 eV
S31 B2 0.001 7.734 eV
S32 B1 0.000 7.773 eV
S33 A2 0.000 7.853 eV
S34 B1 0.000 7.885 eV
S35 A2 0.000 7.913 eV
S36 A2 0.000 7.926 eV
S37 B1 0.000 7.987 eV
S38 B2 0.399 8.020 eV
S39 B2 0.034 8.156 eV
S40 A1 0.016 8.252 eV
S41 A2 0.000 8.261 eV
S42 B1 0.001 8.317 eV
S43 A2 0.000 8.342 eV
S44 B1 0.000 8.352 eV
S45 A1 0.057 8.366 eV
S46 B1 0.002 8.431 eV
S47 B1 0.001 8.446 eV
S48 B2 0.203 8.497 eV
S49 A2 0.000 8.548 eV
S50 B1 0.000 8.607 eV
S51 A2 0.000 8.615 eV
S52 B1 0.001 8.750 eV
S53 A2 0.000 8.778 eV
S54 B1 0.002 8.780 eV
S55 A1 0.003 8.794 eV
S56 A2 0.000 8.810 eV
S57 B2 0.073 8.953 eV
S58 A2 0.000 9.050 eV
S59 B1 0.004 9.065 eV
S60 A2 0.000 9.089 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -14666.59

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:10:32

Legacy ID None

System


Full Name Tricyclo[7.4.1.04,14]tetradeca-1(14),2,4,6,8,10,12-heptaene

Short Name cyclopenta[ef]heptalene

Formula C14H10

Mass 178.2 u

Point Group C2v

Orientation yz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1632 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM