Hexacyclo[12.8.0.02,7.03,21.08,13.017,22]docosa-1(14),2(7),3,5,8,10,12,15,17(22),18,20-undecaene (C22H12) - excitons of #1639

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.013 3.765 eV
S2 A' 0.099 4.059 eV
S3 A' 0.042 4.245 eV
S4 A' 0.010 4.572 eV
S5 A' 0.090 4.713 eV
S6 A' 0.005 5.088 eV
S7 A' 0.206 5.293 eV
S8 A' 0.348 5.374 eV
S9 A' 0.593 5.486 eV
S10 A' 1.235 5.606 eV
S11 A' 0.482 5.826 eV
S12 A' 0.007 5.947 eV
S13 A' 0.348 6.082 eV
S14 A' 0.165 6.297 eV
S15 A' 0.069 6.420 eV
S16 A" 0.000 6.429 eV
S17 A' 0.131 6.473 eV
S18 A" 0.000 6.516 eV
S19 A' 0.008 6.592 eV
S20 A' 0.049 6.707 eV
S21 A' 0.112 6.753 eV
S22 A' 0.118 6.840 eV
S23 A' 0.003 6.884 eV
S24 A' 0.138 6.956 eV
S25 A' 0.023 6.984 eV
S26 A" 0.000 6.988 eV
S27 A' 0.093 7.047 eV
S28 A" 0.001 7.054 eV
S29 A' 0.549 7.131 eV
S30 A' 0.336 7.242 eV
S31 A" 0.000 7.309 eV
S32 A" 0.002 7.343 eV
S33 A" 0.002 7.385 eV
S34 A" 0.000 7.399 eV
S35 A' 0.079 7.407 eV
S36 A" 0.006 7.427 eV
S37 A" 0.000 7.442 eV
S38 A" 0.003 7.490 eV
S39 A' 0.247 7.497 eV
S40 A" 0.000 7.511 eV
S41 A" 0.003 7.581 eV
S42 A' 0.038 7.612 eV
S43 A' 0.308 7.695 eV
S44 A" 0.001 7.700 eV
S45 A' 0.604 7.749 eV
S46 A" 0.000 7.796 eV
S47 A" 0.000 7.824 eV
S48 A' 0.131 7.841 eV
S49 A" 0.002 7.868 eV
S50 A' 0.275 7.963 eV
S51 A" 0.000 7.979 eV
S52 A" 0.000 8.003 eV
S53 A' 0.061 8.007 eV
S54 A" 0.001 8.052 eV
S55 A" 0.001 8.082 eV
S56 A' 0.137 8.085 eV
S57 A" 0.000 8.137 eV
S58 A" 0.000 8.160 eV
S59 A" 0.000 8.227 eV
S60 A' 0.215 8.235 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -22996.67

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:12:08

Legacy ID None

System


Full Name Hexacyclo[12.8.0.02,7.03,21.08,13.017,22]docosa-1(14),2(7),3,5,8,10,12,15,17(22),18,20-undecaene

Short Name dibenz[k,mno]fluoranthene

Formula C22H12

Mass 276.3 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1639 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM