Hexacyclo[14.7.1.02,7.08,24.09,14.017,22]tetracosa-1(23),2,4,6,8(24),9,11,13,15,17,19,21-dodecaene (C24H14) - excitons of #1641

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 A' 0.144 3.439 eV
S2 A' 0.017 3.830 eV
S3 A' 0.213 3.860 eV
S4 A' 0.270 4.473 eV
S5 A' 0.165 4.798 eV
S6 A' 0.323 4.923 eV
S7 A' 0.040 5.128 eV
S8 A' 0.684 5.272 eV
S9 A' 0.402 5.357 eV
S10 A' 0.389 5.498 eV
S11 A' 0.136 5.541 eV
S12 A' 0.541 5.719 eV
S13 A' 0.262 5.921 eV
S14 A' 0.175 5.998 eV
S15 A' 0.534 6.115 eV
S16 A' 0.149 6.147 eV
S17 A" 0.000 6.230 eV
S18 A' 0.069 6.235 eV
S19 A" 0.000 6.360 eV
S20 A' 0.115 6.402 eV
S21 A' 0.030 6.495 eV
S22 A' 0.162 6.553 eV
S23 A' 0.008 6.628 eV
S24 A' 0.489 6.700 eV
S25 A' 0.143 6.751 eV
S26 A' 0.410 6.809 eV
S27 A" 0.000 6.814 eV
S28 A" 0.000 6.906 eV
S29 A" 0.000 6.953 eV
S30 A" 0.000 6.970 eV
S31 A' 0.062 6.990 eV
S32 A' 0.074 7.035 eV
S33 A" 0.000 7.109 eV
S34 A' 0.175 7.261 eV
S35 A' 0.029 7.293 eV
S36 A" 0.000 7.307 eV
S37 A' 0.001 7.363 eV
S38 A" 0.001 7.365 eV
S39 A" 0.000 7.374 eV
S40 A" 0.000 7.399 eV
S41 A' 0.154 7.439 eV
S42 A" 0.001 7.463 eV
S43 A' 0.060 7.466 eV
S44 A" 0.010 7.535 eV
S45 A' 0.054 7.549 eV
S46 A" 0.000 7.568 eV
S47 A" 0.002 7.583 eV
S48 A' 0.094 7.612 eV
S49 A" 0.000 7.651 eV
S50 A" 0.002 7.702 eV
S51 A' 0.085 7.742 eV
S52 A' 0.002 7.767 eV
S53 A" 0.002 7.793 eV
S54 A" 0.000 7.804 eV
S55 A' 0.015 7.818 eV
S56 A" 0.001 7.855 eV
S57 A" 0.001 7.877 eV
S58 A' 0.059 7.888 eV
S59 A' 0.183 7.941 eV
S60 A" 0.004 7.949 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -25103.28

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:12:44

Legacy ID None

System


Full Name Hexacyclo[14.7.1.02,7.08,24.09,14.017,22]tetracosa-1(23),2,4,6,8(24),9,11,13,15,17,19,21-dodecaene

Short Name dibenzo(a,e)fluoranthene

Formula C24H14

Mass 302.4 u

Point Group Cs

Orientation xy

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1641 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM