Hexacyclo[10.10.2.02,7.09,23.013,18.020,24]tetracosa-1(23),2,4,6,8,10,12(24),13,15,17,19,21-dodecaene (C24H14) - excitons of #1643

CAM-B3LYP def2-TZVP 60 roots Orbitals Excitons

TRANSITIONS

MOMENTUM SPACE (Ekin = 30 eV)

EXCITONS / HOLES

S1 0.414 3.277 eV
S2 0.014 3.623 eV
S3 0.000 4.259 eV
S4 0.000 4.590 eV
S5 0.000 4.652 eV
S6 0.000 4.718 eV
S7 2.521 4.871 eV
S8 0.000 5.045 eV
S9 0.063 5.336 eV
S10 0.661 5.389 eV
S11 0.445 5.617 eV
S12 0.000 5.683 eV
S13 0.032 5.822 eV
S14 0.000 5.842 eV
S15 0.000 5.991 eV
S16 0.000 6.102 eV
S17 0.000 6.142 eV
S18 0.544 6.236 eV
S19 0.000 6.407 eV
S20 0.537 6.455 eV
S21 0.001 6.512 eV
S22 0.000 6.527 eV
S23 0.000 6.533 eV
S24 0.000 6.534 eV
S25 0.000 6.667 eV
S26 0.002 6.731 eV
S27 0.000 6.792 eV
S28 0.216 6.804 eV
S29 0.000 6.830 eV
S30 0.677 6.869 eV
S31 0.000 6.895 eV
S32 0.000 6.905 eV
S33 0.000 6.996 eV
S34 0.060 7.100 eV
S35 0.000 7.199 eV
S36 0.000 7.222 eV
S37 0.000 7.233 eV
S38 0.120 7.234 eV
S39 0.044 7.344 eV
S40 0.000 7.349 eV
S41 0.002 7.399 eV
S42 0.000 7.482 eV
S43 0.007 7.486 eV
S44 0.000 7.517 eV
S45 0.000 7.519 eV
S46 0.041 7.551 eV
S47 0.000 7.568 eV
S48 0.001 7.648 eV
S49 0.052 7.680 eV
S50 0.549 7.730 eV
S51 0.071 7.756 eV
S52 0.000 7.756 eV
S53 0.000 7.799 eV
S54 0.000 7.816 eV
S55 0.000 7.834 eV
S56 0.001 7.857 eV
S57 0.255 7.870 eV
S58 0.000 7.895 eV
S59 0.000 7.937 eV
S60 0.001 7.947 eV

Calculation


XC Functional CAM-B3LYP

Basis Set def2-TZVP

Charge 0.0

Spin 0.0

Total Energy [eV] -25103.67

Code Orca 6.1.1

Author Dominik Brandstetter

Date 2025-11-21 09:33:24

Added 2026-09-10 21:13:22

Legacy ID None

System


Full Name Hexacyclo[10.10.2.02,7.09,23.013,18.020,24]tetracosa-1(23),2,4,6,8,10,12(24),13,15,17,19,21-dodecaene

Short Name dibenzo(a,h)pyrene

Formula C24H14

Mass 302.4 u

Point Group C1

Orientation xz

Geometry


Substrate

Light


Energy Mode
Polarization
Handedness

Momentum Space


k-Path


Detector


Real Space


Spectrum


Broadening

Units


Energy Unit

Atoms


Visibility


Orbital


Intensity Scale
Lobe Colours
Density

Scene


Hemisphere

Composition


Hole Position


ID XC Functional Basis Set Code Charge Spin Casida Legacy
1643 CAM-B3LYP def2-TZVP Orca 0.0 0.0

Input File

Output File

Coefficients

Serving Binaries

Transition Matrix

ABSORPTION SPECTRUM